金属氮化物作为锂硫电池阴极硫骨架材料的研究
收稿日期: 2024-07-06
修回日期: 2024-07-31
录用日期: 2024-07-31
网络出版日期: 2024-08-21
Metal Nitrides as Cathode Hosts for Lithium-Sulfur Batteries
Received date: 2024-07-06
Revised date: 2024-07-31
Accepted date: 2024-07-31
Online published: 2024-08-21
由于锂硫电池高理论能量密度（2600 Wh·kg-1）和比容量（1675 mAh·g-1），被认为是集成可再生能源系统用于大规模能量存储的潜在解决方案之一。但由于“穿梭效应”、容量衰减和体积变化等障碍阻碍了锂硫电池的成功商业化。现阶段已提出各种策略以克服技术障碍，本文综述了不同金属氮化物作为高性能锂硫电池阴极宿主材料的应用，总结了不同宿主材料的设计策略，讨论了金属氮化物性质与其电化学性能之间的关系，最后，提出了对金属氮化物设计和发展的合理建议，以及促进未来突破的想法。我们希望本文能够引起更多关于金属氮化物及其衍生物的关注，并进一步促进锂硫电池的电化学性能。
熊海基 , 朱成威 , 邓丁榕 , 吴启辉 . 金属氮化物作为锂硫电池阴极硫骨架材料的研究[J]. 电化学, 2025 , 31(2) : 2407061 . DOI: 10.61558/2993-074X.3489
Lithium-sulfur batteries are considered as one of the potential solutions as integrating renewable energy systems for large-scale energy storage because of their high theoretical energy density (2600 Wh·kg-1) and specific capacity (1675 mAh·g-1). Currently, various strategies have been proposed to overcome the technical barriers, e.g., “shuttle effect”, capacity decay and volumetric change, which impede the successful commercialization of lithium-sulfur batteries. This paper reviews the applications of metal nitrides as the cathode hosts for high-performance lithium-sulfur batteries, summarizes the design strategies of different host materials, and discusses the relationship between the properties of metal nitrides and their electrochemical performances. Finally, reasonable suggestions for the design and development of metal nitrides, along with ideas to promote future breakthroughs, are proposed. We hope that this review could attract more attention to metal nitrides and their derivatives, and further promote the electrochemical performance of lithium-sulfur batteries.
Key words： Lithium-sulfur batteries; Metal nitride; Host material
| [1] | Guo Y, Niu Q, Pei F, Wang Q, Zhang Y, Du L Y, Zhang Y, Zhang Y S, Zhang Y Y, Fan L, Zhang Q Y, Yuan L X, Huang Y X. Interface engineering toward stable lithium-sulfur batteries[J]. Energy Environ. Sci., 2024, 17(4): 1330-1367. |
| [2] | Deng D R, Cui X Y, Wu Q H, Zheng M S, Dong Q F. In-situ synthesis TiO2 nanosheets@rGO for ultrafast sodium ion storage at both room and low temperatures[J]. J. Alloys Compd., 2020, 835: 155413. |
| [3] | Xiong H J, Luo Y L, Deng D R, Zhu C W, Song J X, Weng J C, Wu Q H, Fan X H, Li G F, Zeng Y, Li Y. In-situ synthesis Fe3C@C/rGO as matrix for high performance lithium-sulfur batteries at room and low temperatures[J]. J Colloid Interface Sci., 2024, 668: 448-458. |
| [4] | You Y, Zhang F J, Yu H Z, Li Q, Liu Q Z. Fe2O3-Decorated hollow CNT as efficient cathode coatings for high-performance lithium-sulfur batteries[J]. Mater. Today Commun., 2024, 38: 108479. |
| [5] | Song Y W, Shen L, Yao N, Feng S, Cheng Q, Ma J, Zhang Q, Chen X, Li B Q. Anion-involved solvation structure of lithium polysulfides in lithium-sulfur batteries[J]. Angew. Chem. Int. Ed., 2024, 63(19): e202400343. |
| [6] | Salehi H, Maroufi S, Mofarah S S, Nekouei R K, Sahajwalla V. Recovery of rare earth metals from Ni-MH batteries: A comprehensive review[J]. Renew. Sust. Energ. Rev., 2023, 178: 113248. |
| [7] | Menz F, Bauer M, B?se O, Pausch M, Danzer M A. Investigating the thermal runaway behaviour of fresh and aged large prismatic lithium-ion cells in overtemperature experiments[J]. Batteries, 2023, 9(3): 159-159. |
| [8] | Deng D R, Xiong H J, Luo Y L, Yu K M, Weng J C, Li G F, Wu Q H, Lei J, Zheng M S. Accelerating the rate determining steps of sulfur conversion reaction for lithium-sulfur batteries working at an ultrawide temperature range[J]. Adv. Mater., 2024, 36(39): 2406135. |
| [9] | Li X, Huang J Q, Zhang Q, Mai Q. Nanostructured metal oxides and sulfides for lithium-sulfur batteries[J] Adv. Mater., 2017, 29(20): 1601759. |
| [10] | Wild M, O'neill L, Zhang T, Purkayastha R, Minton G, Marinescu M, Offer G J. Lithium sulfur batteries, a mechanistic review[J]. Energy Environ. Sci., 2015, 8(12): 3477-3494. |
| [11] | Gicha B B, Tufa L T, Nwaji N, Hu X, Lee J. Advances in all-solid-state lithium-sulfur batteries for commercialization[J]. Nano-micro Lett., 2024, 16(1): 172. |
| [12] | Zheng S, Khan N, Worku B E, Wang B. Review and prospect on low-temperature lithium-sulfur battery[J]. Chem. Eng., 2024, 484: 149610. |
| [13] | Liu Y, Wu F, Hu Z, Zhang F, Wang K, Li L, Chen R. Regulating sulfur redox kinetics by coupling photocatalysis for high-performance photo assisted lithium-sulfur batteries[J]. Angew. Chem. Int. Ed., 2024, 63(25): e202402624. |
| [14] | Deng D R, Wu Q H, Li Y. Electronic structure of graphene/MoO3/CuPc interfaces[J]. Mater. Res. Express., 2019, 6(12): 126315. |
| [15] | Song Y Z, Song L X, Wang M L, Cai W L. Chemical vapor deposition making better lithium-sulfur batteries[J]. Sci. Bull., 2024, 16: S2095-9273. |
| [16] | Ji X L, Lee K T, Nazar L F. A highly ordered nanostructured carbon-sulphur cathode for lithium-sulphur battreies[J]. Nat. Mater., 2009, 8(6): 500-506. |
| [17] | Jayaprakash N, Shen J, Moganty S S. Porous hollow cabon@sulfur composites for high-power lithium-sulfur batteries[J]. Angew. Chem. Int. Ed., 2011, 123(26): 6026-6030. |
| [18] | Guo J, Xu Y, Wang C. Sulfur-impregnated disordered cabon nanotubes cathode for lithium-sulfur batteries[J]. Nano Lett., 2011, 11(10): 4288-4294. |
| [19] | Sadd M, De Angelis S, Colding-Jorgensen S. Visualization of dissolution-precipitation procresses in lithium-sulfur batteries[J]. Adv. Energy Mater., 2022, 12(10): 2103126. |
| [20] | Zhu K P, Li L H, Xue P, Pu J, Wu L Y, Guo G D, Wang R, Zhang Y, Peng H S, Hong G, Zhang Q, Yao Y G. “Three-in-one” strategy: Heat regulation and conversion enhancement of a multifunctional separator for safer lithium-sulfur batteries[J]. Carbon Energy, 2023, 5(11): e352. |
| [21] | Wang D W, Zeng Q, Zhou G. Cabon-sulfur composites for Li-S batteries: status and prospects[J]. J. Mater. Chem. A, 2013, 1(33): 9382-9394. |
| [22] | Fei B, Zhang C, Cai D. Hierarchical nanoreactor with multiple adsorption and catalytic sites for robust lithium-sulfur batteries[J]. ACS nano, 2021, 15(4): 6849-6860. |
| [23] | Hu X C, Zhu X S, Ran Z S, Liu S H, Zhang Y Y, Wang H, Wei W. Conductive polymer-based interlayers in restraining the polysulfide shuttle of lithium-sulfur batteries[J]. Molecules, 2024, 29(5): 1164. |
| [24] | Fei Y, Li G. Unveiling the pivotal parameters for advancing high energy density in lithium-sulfur batteries: a comprehensive review[J]. Adv. Funct. Mater., 2024, 34(21): 2312550. |
| [25] | Song Z H, Jiang W Y, Li B R, Qu Y P, Mao R Y, Jian X G, Hu F Y. Advanced polymers in cathodes and electrolytes for lithium-sulfur batteries: progress and prospects[J]. Small, 2024, 20(19): 2308550. |
| [26] | Chen J J, Fu Y Q, Guo J C. Development of electrolytes under lean condition in lithium-sulfur batteries[J]. Adv. Mater., 2024, 36(29): 2401263. |
| [27] | Deng D R, Xue F, Bai C D, Lei J, Yuan R M, Sen Zheng M, Dong Q F. Enhanced adsorptions to polysulfides on graphene-supported BN nanosheets with excellent Li-S battery performance in a wide temperature range[J]. ACS Nano, 2018, 12(11): 11120-11129. |
| [28] | Deng D R, Cui X Y, Fan X X, Zheng J Q, Fan X H, Wu Q H, Zheng M S, Dong Q F. Integration of adsorption and catalytic active sites in cobalt iron oxide nanorods for an excellent performance Li-S battery with a wide temperature range[J]. Sustain. Energy. Fuels., 2021, 5(17): 4284-4288. |
| [29] | Borchardt L, Oschatz M, Kaskel S. Carbon materials for lithium sulfur batteries-ten critical questions[J]. Chem. Eur. J., 2016, 22(22): 7324-7351. |
| [30] | Dasarathan S, Sung J H, Ali M, Lee Y J, Choi H Y, Park J W, Kim D. Effect of phosphorus-modified TiN mesoporous MXene interlayer as a polysulfide electrocatalyst in Li-S battery[J]. Electrochem. Commun., 2024, 160: 107679. |
| [31] | Yin R J, Wan L, Xue H T, Wei C D, Liu M W, Zhao W, Tang F L. First-principles study of the catalytic performance of sulfur cathode host Co3Mo3N[J]. Comput. Mater. Sci., 2024, 238: 112946. |
| [32] | Lu S, Cai L C, Wang J Q, Ying H J, Han Z K, Han W Q, Chen Z P. 2D ultrathin titanium nitride nanosheets as separator coatings for Li-S batteries[J]. Small, 2024, 20(27): 2307784. |
| [33] | Liu R Q, He L L, Liu Y R, Wu J Y, Zhu W F, Xie K, Liu W X, Lin X J, Shi L, Wang S, Feng X M, Ma Y W. Multistep C/VN frameworks as highly-efficient sulfur host for high-performance lithium-sulfur batteries[J]. Mater. Chem. Phys., 2024, 315: 129045. |
| [34] | Liu J T, Yu L H, Ran Q W, Chen X A, Wang X Y, He X D, Jin H L, Chen T, Chen J S, Guo D Y, Wang S. Regulating electron filling and orbital occupancy of anti-bonding states of transition metal nitride heterojunction for high areal capacity lithium-sulfur full batteries[J]. Small, 2024, 20(31): 2311750. |
| [35] | Kadam S A, Jose L M, George N S, Sreehari S, Nayana D A, Van Pham D, Kadam K P, Aravind A, Ma Y R. Recent progress in transition metal nitride electrodes for supercapacitor, water splitting, and battery applications[J]. J. Alloys Compd., 2023, 976: 173083. |
| [36] | Wang T, Dong Q, Wang F Z, Xu R, Tong C, Su D, Shao M H, Li C P, Wei Z D. Functionless cobalt toward functional cobalt nitride: Catalytic sulfur carrier for lithium-sulfur pouch batteries[J]. Matter., 2024, 7(3): P1035-1053. |
| [37] | Jin L N, Chen J Y, Fu Z H, Qian X Y, Cheng J, Hao Q Y, Zhang K. ZIF-8/ZIF-67 derived ZnS@Co-NC hollow core-shell composite and its application in lithium?sulfur battery[J]. SM&T, 2023, 35(6): e00571. |
| [38] | Zhang P, Yue L L, Liang Q Y, Gao H, Yan Q, Wang L. a review of transition metal compounds as functional separators for lithium-sulfur batteries[J]. ChemistrySelect, 2023, 8(1): e202203352. |
| [39] | Li J, Zhang X, Zhang Z Y, Li Y R, Zhu L L. Preparation of LDHs-derived Co-Ni3N heterostructure modified porous carbon nanofibers as advanced interlayers for lithium-sulfur batteries[J]. J. Alloys Compd., 2024, 971: 72731. |
| [40] | Mori R. Cathode materials for lithium-sulfur battery: a review[J]. J. Solid State Electrochem., 2023, 27(4): 813-839. |
| [41] | Zhang X D, Zhao M C, Cai D P, Zhang C Q, Chen Q D, Zhan H B. Separator modified by ternary iron molybdenum nitride and nitrogen-doped carbon composite enabling efficient polysulfide conversion for lithium-sulfur batteries[J]. J. Alloys Compd., 2023, 967: 171633. |
| [42] | Han Z, Son S, Kim K, Geng M Z, Yang H Q. Manganese nitride/oxide heterostructure interlayer derived from triazolate metal-organic framework for stable Li-S batteries[J]. Chem. Eng. J., 2024, 481: 148389. |
| [43] | Wang Y K, Zhang R F, Pang Y C, Chen X, Lang J X, Xu J J, Xiao C H, Li H L, Xi K, Ding S J. Carbon@titanium nitride dual shell nanospheres as multi-functional hosts for lithium sulfur batteries[J]. Energy Stor. Mater., 2019, 16: 228-235. |
| [44] | Ma L B, Wang Y R, Wang Z W, Wang J L, Cheng Y W, Wu J X, Peng B, Xu J, Zhang W, Jin Z. Wide-temperature operation of lithium-sulfur batteries enabled by multi-branched vanadium nitride electrocatalyst[J]. ACS Nano., 2023, 17(12): 11527-11536. |
| [45] | Yang J, Li S Q, Wu G Z, Bao J W, Xu S, Gu C P, Lv J J, Huang J R, Joo S W. Preparation of polyaniline-coated cobalt nitride nanoflowers as sulfur host for advanced lithium-sulfur battery[J]. J. Alloys Compd., 2024, 981: 173701-173701. |
| [46] | Deng D J, Zhang H H, Wu J C, Tang X, Ling M, Dong S H, Xu L, Li H A, Li H M. Electronic structure and spin state regulation of vanadium nitride via a sulfur doping strategy toward flexible zinc-air batteries[J]. J. Energy Chem., 2024, 89: 239-249. |
| [47] | Sekiya T, Yamada T, Yamane H. Synthesis of faceted crystal grains of titanium nitride using titanium oxides, boron nitride, and sodium[J]. J. Chem. Soc. Japan, 2020, 128(7): 364-367. |
| [48] | Xu W C, Pan X X, Meng X, Zhang Z H, Peng H R, Liu J, Li G C. A conductive sulfur-hosting material involving ultrafine vanadium nitride nanoparticles for high-performance lithium-sulfur battery[J]. Electrochim. Acta, 2020, 331: 135287-135287. |
| [49] | Xie D, Wang X T, Wei L J, Zhang R, Ganesan R, Matthews D T A, Leng Y X. Atomic configuration, electronic structure, and work of adhesion of TiN (111)//B2-NiTi (110) and TiN (111)//B19′-NiTi (010) interfaces: Insights from first-principles simulations[J]. Surf. Interface Anal., 2023, 55(1): 41-51. |
| [50] | Morales H M, Vieyra H, Sanchez D A, Fletes E M, Odlyzko M, Lodge T P, Padilla-Gainza V, Alcoutlabi M, Parsons J G. Synthesis and characterization of titanium nitride-carbon composites and their use in lithium-ion batteries[J]. Nanomaterials, 2024, 14(7): 624. |
| [51] | Avasarala B, Haldar P. Electrochemical oxidation behavior of titanium nitride based electrocatalysts under PEM fuel cell conditions[J]. Electrochim. Acta, 2010, 55(28): 9024-9034. |
| [52] | Lu X H, Wang G M, Zhai T, Yu M H, Xie S L, Ling Y C, Liang C L, Tong Y X, Li Y. Stabilized TiN nanowire arrays for high-performance and flexible supercapacitors[J]. Nano Lett., 2012, 12(10): 5376-5381. |
| [53] | Cui Z M, Zu C X, Zhou W D, Manthiram A, Goodenough J B. Mesoporous titanium nitride-enabled highly stable lithium-sulfur batteries[J]. Adv. Mater., 2016, 28(32): 6926-6931. |
| [54] | Deng D R, An T H, Li Y J, Wu Q H, Zheng M S, Dong Q F. Hollow porous titanium nitride tubes as a cathode electrode for extremely stable Li-S batteries[J]. J. Mater. Chem. A, 2016, 4(41): 16184-16190. |
| [55] | Deng D R, Wu Q H. Hollow TiN microspheres synthesized by a template-free method as a matrix for high performance Li-S battery[J]. ChemistrySelect, 2020, 5(28): 8735-8739. |
| [56] | Zhao J, Zhao Y Y, Yue W C, Li X, Gao N, Zhang Y J, Hu C Q. V2O3/VN catalysts decorated free-standing multifunctional interlayer for high-performance Li-S battery[J]. Chem. Eng. J., 2022, 441: 136082. |
| [57] | Cai D P, Zhuang Y X, Fei B, Zhang C Q, Wang Y G, Chen Q D, Zhan H B. Self-supported VN arrays coupled with N-doped carbon nanotubes embedded with Co nanoparticles as a multifunctional sulfur host for lithium-sulfur batteries[J]. Chem. Eng. J., 2022, 430(P3): 132931. |
| [58] | Wang L, Sun C Y, Ji S, Linkov V, Wang H. Highly-dispersed vanadium nitride supported on porous nitrogen-doped carbon material as a high-performance cathode for lithium-sulfur batteries[J]. ChemistrySelect, 2022, 7(45): e202202879. |
| [59] | Sun C Y, Ji S, Ma X G, Wang H, Wang X Y, Linkov V, Wang R F. Using sp2 N atom anchoring effect to prepare ultrafine vanadium nitride particles on porous nitrogen-doped carbon as cathode for lithium-sulfur battery[J]. J. Colloid Interface Sci., 2022, 623: 306-317. |
| [60] | Azouaoui A, Benzakour N, Hourmatallah A, Bouslykhane K. Study of structural, electronic, magnetic, elastic, and thermodynamic properties of Co4N antiperovskite by first principles and Monte Carlo simulation[J]. Phys. Status Solidi B, 2021, 258(2): 2000339. |
| [61] | Jia H N, Fan J H, Su P, Guo T T, Liu M C. Cobalt nitride nanoparticles encapsulated in N-doped carbon nanotubes modified separator of Li-S battery achieving the synergistic effect of restriction adsorption catalysis of polysulfides[J]. Small, 2024, 20(26): 2311343. |
| [62] | Xiao K K, Wang J, Chen Z, Qian Y H, Liu Z, Zhang L L, Chen X H, Liu J L, Fan X F, Shen Z X. Improving polysulfides adsorption and redox kinetics by the Co4N nanoparticle/N-doped carbon composites for lithium-sulfur batteries[J]. Small, 2019, 15(25): 1901454. |
| [63] | Li Z Q, Li C X, Ge X L, Ma J Y, Zhang Z W, Li Q, Wang C X, Yin L W. Reduced graphene oxide wrapped MOFs-derived cobalt-doped porous carbon polyhedrons as sulfur immobilizers as cathodes for high performance lithium-sulfur batteries[J]. Nano Energy, 2016, 23: 15-26. |
| [64] | Deng D R, Xue F, Jia Y J, Ye J C, Bai C D, Zheng M S, Dong Q F. Co4N nanosheet assembled mesoporous sphere as a matrix for ultrahigh sulfur content lithium-sulfur batteries[J]. ACS nano, 2017, 11(6): 6031-6039. |
| [65] | Wang Z, Wang X, Tong Y G, Wang Y P. Impact of structure and flow-path on in situ synthesis of AlN: Dynamic microstructural evolution of Al-AlN-Si materials[J]. Sci. China Mater., 2018, 61(7): 948-960. |
| [66] | Jackson N, Mathewson A. Enhancing the piezoelectric properties of flexible hybrid AlN materials using semi-crystalline parylene[J]. Smart Mater. Struct., 2017, 26(4): 045005. |
| [67] | Hou X R, Li L, Wei S C, Li J D, Wu F C. Two-dimension Al2O3-AlN heterogeneous nanosheets as bifunctional host materials for kinetics-accelerated and dendrite-free lithium-sulfur batteries[J]. Electrochim. Acta, 2023, 464: 142887. |
| [68] | Yang J, Wu G Z, Sun A J, Gu C P, Cao Y X, Joo S W, Huang J R. AlN nanoparticles anchored on cross-linked N-doped carbon nanosheets as sulfur hosts for lithium-sulfur battery[J]. J. Electroanal. Chem., 2023, 951: 117930. |
| [69] | Abdelkader H S, Rabahi A, Benaissa M, Benabadji M K. Theoretical investigation of structural and mechanical stability of Mo2N[J]. Solid State Commun., 2020, 314-315: 113919. |
| [70] | Yang J L, Cai D Q, Lin Q W, Wang X Y, Fang Z Q, Huang L, Wang Z J, Hao X G, Zhao S X, Li J, Cao G Z, Lv W. Regulating the Li2S deposition by grain boundaries in metal nitrides for stable lithium-sulfur batteries[J]. Nano Energy, 2022, 91: 106669. |
| [71] | Jiang G S, Xu F, Yang S H, Wu J P, Wei B Q, Wang H Q. Mesoporous, conductive molybdenum nitride as efficient sulfur hosts for high-performance lithium-sulfur batteries[J]. J. Power Sources, 2018, 395: 77-84. |
| [72] | Liu H D, Chen Z L, Man H, Yang S P, Song Y, Fang F, Chen R C, Sun D L. Template-guided synthesis of porous MoN microrod as an effective sulfur host for high-performance lithium-sulfur batteries[J]. J. Alloys Compd., 2020, 842: 155764. |
| [73] | Xing W D, Zhang Y, Meng F Y, Wang C C, Tao Q, Zhu P W, Zhu J, Yu R. Structure stabilization effect of configuration entropy in cubic WN[J]. Phys. Chem. Chem. Phys., 2018, 20(46): 29243-29248. |
| [74] | Yan N F, Cui H M, You S Y, Shi J S, Weng Y Q, Liu Y W. Tungsten nitride nanotubes as sulfur host material for high performance Li-S batteries[J]. Inorg. Chem. Commun., 2022, 140: 109458. |
| [75] | Liu H, Shen H, Li R, Liu S, Turak A, Yang M. Tungsten-nitride-coated carbon nanospheres as a sulfur host for high-performance lithium-sulfur batteries[J]. ChemElectroChem, 2019, 6(7): 2074-2079. |
| [76] | Huang Z D, Fang Y W, Yang M T, Yang J K, Wang Y Z, Wu Z, Du Q C, Masese T, Liu R Q, Yang X S, Qian C H, Jin S W, Ma Y W. Sulfur in mesoporous tungsten nitride foam blocks: a rational lithium polysulfide confinement experimental design strategy augmented by theoretical predictions[J]. ACS Appl. Mater. Interfaces, 2019, 11(22): 20013-20021. |
| [77] | Mosavati N, Salley S O, Ng K Y S. Characterization and electrochemical activities of nanostructured transition metal nitrides as cathode materials for lithium sulfur batteries[J]. J. Power Sources, 2017, 340: 210-216. |
| [78] | Sun Z H, Zhang J Q, Yin L C, Hu G J, Fang R P, Cheng H M, Li F. Conductive porous vanadium nitride/graphene composite as chemical anchor of polysulfides for lithium-sulfur batteries[J]. Nat. Commun., 2017, 8: 14627. |
| [79] | D R Deng, Xue F, Jia Y J, Ye J C, Bai C D, Zheng M S, Dong Q F. Co4N nanosheet assembled mesoporous sphere as a matrix for ultrahigh sulfur content lithium-sulfur batteries[J]. ACS Nano, 2017, 11(6): 6031-6039. |
| [80] | Zhang H, Ono L K, Tong G Q, Liu Y Q, Qi Y B. Long-life lithium-sulfur batteries with high areal capacity based on coaxial CNTs@TiN-TiO2 sponge[J]. Nat. Commun., 2021, 12(1): 4738. |
| [81] | Liu Z H, Lian R Q, Wu Z R, Li Y J, Lai X Y, Yang S, Ma X, Wei Y J, Yan X. Ordered dual-channel carbon embedded with molybdenum nitride catalytically induced high-performance lithium-sulfur battery[J]. Chem. Eng. J., 2022, 431(P2): 134163-134163. |
| [82] | Deng D R, Wu Q H. Hollow TiN microspheres synthesized by a template-free method as a matrix for high performance Li-S battery[J]. ChemistrySelect, 2020, 5(28): 8735-8739. |
| [83] | Yao Y, Wang H Y, Yang H, Zeng S F, Xu R, Liu F F, Shi P C, Feng Y Z, Wang K, Yang W J, Wu X J, Luo W, Yu Y. A dual-functional conductive framework embedded with TiN-VN heterostructures for highly efficient polysulfide and lithium regulation toward stable Li-S full batteries[J]. Adv. Mater., 2020, 32(6): 1905658. |
| [84] | Wang Y K, Zhang R F, Sun Z H, Wu H, Lu S Y, Wang J N, Yu W, Liu J M, Gao G X, Ding S J. Spontaneously formed Mott-Schottky electrocatalyst for lithium-sulfur batteries[J]. Adv. Mater., Interfaces 2020, 7(22): 1902092. |
| [85] | He J R, Manthiram A. Long-life, high-rate lithium-sulfur cells with a carbon-free VN host as an efficient polysulfide adsorbent and lithium dendrite inhibitor[J]. Adv. Energy Mater., 2020, 10(3): 1903241. |
| [86] | Xiao X, Wang H, Bao W Z, Urbankowski P, Yang L, Yang Y, Maleski K, Cu L F, Billinge S J L, Wang G X, Gogotsi Y. Two-dimensional arrays of transition metal nitride nanocrystals[J]. Adv. Mater., 2019, 31(33): 1902393. |
| [87] | Mosavati N, Chitturi V R, Salley S O, Ng K Y S. Nanostructured titanium nitride as a novel cathode for high performance lithium/dissolved polysulfide batteries[J]. J. Power Sources, 2016, 321: 87-93. |
| [88] | Chen L, Yang W W, Zhang H, Liu J G, Zhou Y. Self-templated preparation of hollow mesoporous TiN microspheres as sulfur host materials for advanced lithium-sulfur batteries[J]. J. Mater. Sci., 2018, 53(14): 10363-10371. |
| [89] | Liu D, Wang Z C, Guo Z C, Tian Y, Wang C. Electrospun CuCoN0.6 coating necklace-like N-doped carbon nanofibers for high performance lithium-sulfur batteries[J]. J. Colloid Interface Sci., 2023, 645: 705-714. |
| [90] | Liu J T, Yu L H, Ran Q W, Chen X A, Wang X Y, He X D, Jin H L, Chen T, Chen J S, Guo D Y, Wang S. Regulating electron filling and orbital occupancy of anti-bonding states of transition metal nitride heterojunction for high areal capacity lithium-sulfur full batteries[J]. Small, 2024: 2311750. |
| [91] | Sun C Y, Ji S, Ma X G, Wang H, Wang X Y, Linkov V, Wang R F. Using sp2 N atom anchoring effect to prepare ultrafine vanadium nitride particles on porous nitrogen-doped carbon as cathode for lithium-sulfur battery[J]. J. Colloid Interface Sci., 2022, 623: 306-317. |
| [92] | Lv J J, Ren H B, Cheng Z Y, Joo S W, Huang J R. Polyaniline-coated porous vanadium nitride microrods for enhanced performance of a lithium-sulfur battery[J]. Molecules, 2023, 28(4): 1823. |
| [93] | Li X X, Ding K, Gao B, Li Q W, Li Y Y, Fu J J, Zhang X M, Chu P K, Huo K F. Freestanding carbon encapsulated mesoporous vanadium nitride nanowires enable highly stable sulfur cathodes for lithium-sulfur batteries[J]. Nano Energy, 2017, 40: 655-662. |
| [94] | Pang Q, Kundu D, Nazar L F. A graphene-like metallic cathode host for long-life and high-loading lithium-sulfur batteries[J]. Mater. Horizons, 2016, 3(2): 130-136. |
| [95] | Hart C J, Cuisinier M, Liang X, Kundu D, Garsuch A, Nazar L F. Rational design of sulphur host materials for Li-S batteries: correlating lithium polysulphide adsorptivity and self-discharge capacity loss[J]. ChemComm, 2015, 51(12): 2308-2311. |
| [96] | Song J X, Xu T, Gordin M L, Zhu P Y, Lv D P, Jiang Y B, Chen Y S, Duan Y H, Wang D H. Nitrogen-doped mesoporous carbon promoted chemical adsorption of sulfur and fabrication of high-areal-capacity sulfur cathode with exceptional cycling stability for lithium-sulfur batteries[J]. Adv. Funct. Mater., 2014, 24(9): 1243-1250. |
| [97] | Hou T Z, Peng H J, Huang J Q, Zhang Q, Li B. The formation of strong-couple interactions between nitrogen-doped graphene and sulfur/lithium (poly) sulfides in lithium-sulfur batteries[J]. 2D Mater., 2015, 2(1): 014011. |
| [98] | Peng H J, Zhang G, Chen X, Zhang Z W, Xu W T, Huang J Q, Zhang Q. Enhanced electrochemical kinetics on conductive polar mediators for lithium-sulfur batteries[J]. Angew. Chem. Int. Ed., 2016, 55(42): 12990-12995. |
| [99] | Wang H T, Zhang Q F, Yao H B, Liang Z, Lee H W, Hsu P C, Zheng G Y, Cui Y. High electrochemical selectivity of edge versus terrace sites in two-dimensional layered MoS2 materials[J]. Nano Lett., 2014, 14(12): 7138-7144. |
| [100] | Zhao M, Li B Q, Peng H J, Yuan H, Wei J Y, Huang J Q. Lithium-sulfur batteries under lean electrolyte conditions: Challenges and opportunities[J]. Angew. Chem. Int. Ed., 2020, 59I(31): 12636-12652. |
| [101] | Kamali A R, Fray D J. Tin-based materials as advanced anode materials for lithium ion batteries: a review[J]. Rev. Adv. Mater. Sci, 2011, 27(1): 14-24. |
| [102] | Yang Z G, Xu H M, Shuai T Y, Zhan Q N, Zhang Z J, Huang K, Dai C L, Li G R. Recent progress in the synthesis of transition metal nitride catalysts and their applications in electrocatalysis[J]. Nanoscale, 2023, 15(28): 11777-11800. |
/
| 〈 |
|
〉 |
