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电加热微电极传热模式的结构依赖性研究

  • 李炬 ,
  • 杨森 ,
  • 孙建军
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  • a河南工贸职业学院,河南 郑州 451191
    b郑州大学药学院,河南省肿瘤重大疾病靶向治疗与诊断重点实验室,教育部药物关键制备技术重点实验室,药物安全性评价研究中心,河南 郑州 450001
    c福州大学化学学院,教育部食品安全与生物分析科学重点实验室,福建省食品安全分析检测技术重点实验室,福建 福州 350108

收稿日期: 2022-03-21

  修回日期: 2022-04-27

  录用日期: 2022-04-28

  网络出版日期: 2022-05-07

Dependence of Heat Transfer Model on the Structure of Electrically Coil-Heated Microelectrodes

  • Ju Li ,
  • Sen Yang ,
  • Jian-Jun Sun
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  • aSchool of Henan Industry and Trade Vocational College, Zhengzhou, Henan Province 451191, China
    bKey Laboratory of Targeting Therapy and Diagnosis for Critical Diseases, Henan Province, Key laboratory of Advanced Drug Preparation Technologies, Ministry of Education, Collaborative Innovation Center of New Drug Research and Safety Evaluation, Scbn hool of Pharmaceutical Sciences, Zhengzhou University, Zhengzhou, 450001, China
    cMinistry of Education Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
Tel: (86-591)22866136, E-mail: jjsun@fzu.edu.cn
*Tel: (86-371)67781891, E-mail: liju1124@zzu.edu.cn;

Received date: 2022-03-21

  Revised date: 2022-04-27

  Accepted date: 2022-04-28

  Online published: 2022-05-07

摘要

近年来,电加热微电极在电分析化学中得到了广泛的关注。研究表明,在高温下促进质量传输和反应动力学通常会导致电流信号增加。然而,目前还没有关于微电极内部传热的研究,这对于微传感器的设计和操作是必要的。本文利用有限元模拟软件(COMSOL)来分析影响表面温度(Ts)的因素,这对线圈加热的微盘电极的加热能力至关重要。电极表面和加热铜线底部之间的距离也与TsR2 = 1)有良好的线性关系。考虑到成本,25 mm长的金丝足以获得相对较高的Ts。此外,当电极材料为金且金盘直径为0.2 mm时,可以获得最高的Ts。本文还研究了不同温度下加热铜线直径与电流的关系。仿真结果有望为电加热微传感器的设计和实际应用提供重要帮助。

本文引用格式

李炬 , 杨森 , 孙建军 . 电加热微电极传热模式的结构依赖性研究[J]. 电化学, 2023 , 29(9) : 2203211 . DOI: 10.13208/j.electrochem.2203211

Abstract

Electrically heated microelectrodes have gained much attention in electroanalytical chemistry in recent years. It has been shown that the promotion of mass transport and reaction kinetics at high-temperatures often results in increased current signals. However, there is no study about the heat transfer inner the microelectrodes which is necessary for the design and operation for microsensors. This report introduces a finite element software (COMSOL) to analyze the factors that influence the surface temperature (Ts), which is crucial for the heating ability of micro-disk electrodes with coils. Distances between the electrode surface and the bottom of the heated copper wire also have a good linear relationship with Ts (R2 = 1). Considering the cost, 25-mm length of the gold wire is enough to obtain a relatively high Ts. In addition, the highest Ts can be obtained when the electrode material is gold and the diameter of the gold disk is 0.2 mm. The relationship of diameters of heated copper wires with currents to obtain different temperatures has also been studied. It is expectable that the simulation results can be used to significantly help the design and operation of electrically heated microsensors in practical applications.

参考文献

[1] Gründler P, Zerihun T, M?ller A, Kirbs A. A simple method for heating micro electrodes in-situ[J]. J. Electroanal. Chem., 1993, 360: 309-314.
[2] Grundler P, Zerihun T, Kirbs A, Grabow H. Simultaneous joule heating and potential cycling of cylindrical microelectrodes[J]. Anal. Chim. Acta, 1995, 305(1-3): 232-240.
[3] Zerihun T, Griindler P. Electrically heated cylindrical microelectrodes.The reduction of dissolved oxygen on Pt[J]. J. Electroanal. Chem., 1996, 404: 243-248.
[4] Valdes J L, Miller B. Thermal modulation of rotating disk electrodes: Steady-state response[J]. J. Phys. Chem., 1988, 92: 525-532.
[5] Gründler P, Degenring D. The limits of aqueous hot-wire electrochemistry: Near-critical and supercritical fluids in electrochemical sensors?[J]. Electroanalysis, 2001, 13: 755-759.
[6] Baranski A S. Hot microelectrodes[J]. Anal. Chem., 2002, 74: 1294-1301.
[7] Wildgoose G G, Giovanelli D, Lawrence N S, Compton R G. High-temperature electrochemistry: A review[J]. Electroanalysis, 2004, 16(6): 421-433.
[8] Gründler P, Flechsig G U. Principles and analytical applications of heated electrodes[J]. Microchim. Acta, 2006, 154(3-4): 175-189.
[9] Grundler P, Kirbs A, Dunsch L. Modern thermoelectrochemistry[J]. Chemphyschem, 2009, 10(11): 1722-1746.
[10] Cutress I J, Marken F, Compton R G. Microwave-assisted electroanalysis: A review[J]. Electroanalysis, 2009, 21(2): 113-123.
[11] Flechsig G U, Walter A. Electrically heated electrodes: Practical aspects and new developments[J]. Electroanalysis, 2012, 24(1): 23-31.
[12] Wang J, Grulndler P, Flechsig G U, Jasinski M, Rivas G, Sahlin E, Paz J L L. Stripping analysis of nucleic acids at a heated carbon paste electrode[J]. 2000, 72, 16: 3752-3756.
[13] Tsai Y C, Coles B A, Compton R G, Marken F. Microwave activation of electrochemical processes: Enhanced electrodehalogenation in organic solvent media[J]. J. Am. Chem. Soc., 2002, 124(33): 9784-9788.
[14] Wei H, Sun J J, Guo L, Li X, Chen G N. Highly enhanced electrocatalytic oxidation of glucose and shikimic acid at a disposable electrically heated oxide covered copper electrode[J]. Chem. Commun., 2009, (20): 2842-2844.
[15] Walter A, Surkus A E, Flechsig G U. Hybridization detection of enzyme-labeled DNA at electrically heated electrodes[J]. Anal. Bioanal. Chem., 2013, 405(11): 3907-3911.
[16] Huang Z X, Yang S, Guo J W, Wu S H, Sun J J, Chen G N. Supercooled electrodes[J]. Electrochem. Commun., 2014, 48: 107-110.
[17] Huang Z X, Yang S, Yao F Z, Xu K X, Zhang J F, Wu S H, Sun J J. Alternate hot and cold electrodes[J]. Electrochem. Commun., 2015, 61: 129-133.
[18] Yang S, Huang Z X, Hou X H, Cheng F F, Wu S H, Sun J J. A model for understanding the temperature change of an alternate hot and cold micro-band graphite electrode[J]. Electrochem. Commun., 2016, 68: 71-75.
[19] Yang S, Chen X, Mi Z Z, Chen Z M, Li X D, Sun J J, Wu S H. Temperature-controllable electrodes with a one-parameter calibration[J]. ACS Sens., 2019, 4(6): 1594-1602.
[20] Chen Z M, Wang Y, Du X Y, Sun J J, Yang S. Temperature-alternated electrochemical aptamer-based biosensor for calibration-free and sensitive molecular measurements in an unprocessed actual sample[J]. Anal. Chem., 2021, 93(22): 7843-7850.
[21] Ma B, Wang L, He K, Li D G, Liang X D. A lattice boltzmann analysis of the electro-thermo convection and heat transfer enhancement in a cold square enclosure with two heated cylindrical electrodes[J]. Int. J. Therm. Sci., 2021, 164: 106885.
[22] Wu S H, Zhu B J, Huang Z X, Sun J J. A heated pencil lead disk electrode with direct current and its preliminary application for highly sensitive detection of luteolin[J]. Electrochem. Commun., 2013, 28: 47-50.
[23] Wu S H, Tang Y, Chen L, Ma X G, Tian S M, Sun J J. Amplified electrochemical hydrogen peroxide reduction based on hemin/g-quadruplex dnazyme as electrocatalyst at gold particles modified heated copper disk electrode[J]. Biosens. Bioelectron., 2015, 73: 41-46.
[24] Wu S H, Zeng Y F, Chen L, Tang Y, Xu Q L, Sun J J. Amplified electrochemical DNA sensor based on hemin/g-quadruplex dnazyme as electrocatalyst at gold particles modified heated gold disk electrode[J]. Sens. Actuator B-Chem., 2016, 225: 228-232.
[25] Wu S H, Zhang B, Wang F F, Mi Z Z, Sun J J. Heating enhanced sensitive and selective electrochemical detection of Hg2+ based on T-Hg2+-T structure and exonuclease iii-assisted target recycling amplification strategy at heated gold disk electrode[J]. Biosens. Bioelectron., 2018, 104: 145-151.
[26] Beckmann A, Coles B A, Compton R G, Gründler P, Marken F, Neudeck A. Modeling hot wire electrochemistry. Coupled heat and mass transport at a directly and continuously heated wire[J]. 2000, 104(4): 764-769.
[27] Baranski A S. Hot microelectrodes[J]. Anal. Chem., 2002, 74(6): 1294-1301.
[28] Boika A, Baranski A S. Dielectrophoretic and electrothermal effects at alternating current heated disk microelectrodes[J]. Anal. Chem., 2008, 80: 7392-7400.
[29] Baranski A S, Boika A. Ultrahigh frequency voltammetry: Effect of electrode material and frequency of alternating potential modulation on mass transport at hot-disk microelectrodes[J]. Anal. Chem., 2012, 84(3): 1353-1359.
[30] Qiu F, Compton R G, Coles B A, Marken F. Thermal activation of electrochemical processes in a rf-heated channel flow cell: Experiment and finite element simulation[J]. J. Electroanal. Chem., 2000, 492(2): 150-155.
[31] Gabrielli C, Keddam M, Lizee J F. Frequency analysis of a temperature perturbation technique in electrochemistry : Part i. Theoretical aspects[J]. J. Electroanal. Chem., 1993, 359(1-2): 1-20.
[32] Gabrielli C. A transfer function approach for a generalized electrochemical impedance spectroscopy[J]. J. Electrochem. Soc., 1994, 141(5): 1147-1157.
[33] Mahnke N, Markovic A, Duwensee H, Wachholz F, Flechsig G U, van Rienen U. Numerically optimized shape of directly heated electrodes for minimal temperature gradients[J]. Sens. Actuator B-Chem., 2009, 137(1): 363-369.
[34] Frischmuth K, Visocky P, Gründler P. On modelling heat transfer in chemical microsensors[J]. Int. J. Eng. Sci., 1996, 34(5): 523-530.
[35] Jenkins D M, Song C, Fares S, Cheng H, Barrettino D. Disposable thermostated electrode system for temperature dependent electrochemical measurements[J]. Sens. Actuator B-Chem., 2009, 137(1): 222-229.
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