基于纳米金属的增强效应在CO2电还原反应中的应用进展
收稿日期: 2020-05-21
修回日期: 2020-06-12
网络出版日期: 2020-06-28
基金资助
国家自然科学基金项目资助(21972042)
Recent Progress on Enhancing Effect of Nanosized Metals for Electrochemical CO2 Reduction
Received date: 2020-05-21
Revised date: 2020-06-12
Online published: 2020-06-28
张钰宁 , 钮东方 , 胡硕真 , 张新胜 . 基于纳米金属的增强效应在CO2电还原反应中的应用进展[J]. 电化学, 2020 , 26(4) : 495 -509 . DOI: 10.13208/j.electrochem.200446
The electrochemical conversion of CO2 to chemical raw material for further utilization shows promising future to alleviate global warming and realize carbon cycle in nature, which is of great significance to the green chemistry and sustainable development. This review briefly introduces the advantages of CO2 electrochemical reduction (CO2ER) and its basic reaction principles, and summarizes the recent progress in a series of activity enhancement strategies based on nanosized metal catalysts. The influences of alloy effect, interface engineering, synergistic effect, surface defect engineering and support effect on the catalytic performance of nanosized metals for CO2ER and the related reaction mechanisms are mainly reviewed. Based on the above strategy, the challenges and prospects for the future development of CO2ER catalysts for industrial applications are proposed.
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