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研究论文

柔性ZnNi/Al-LDHs/碳纤维复合材料的制备及光-电催化特性

  • 田晶晶 ,
  • 陈涛 ,
  • 包星辰 ,
  • 高梦旭 ,
  • 于业笑 ,
  • 彭思遥 ,
  • 晋冠平
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  • 合肥工业大学化学化工学院,合肥可控化学反应及材料化工重点实验室,安徽 合肥 230009

收稿日期: 2017-07-27

  修回日期: 2017-09-12

  网络出版日期: 2022-01-07

基金资助

国家自然科学基金 (NSFC, No. U140710231)和国家级大学生创新训练计划项目 (No. 201710359028).

Electrochemical Preparation and Photo-Electro Catalytic Properties of Flexible ZnNi/Al-LDHs/Carbon Fibers Composite

  • TIAN Jing-jing ,
  • CHEN Tao ,
  • BAO Xing-chen ,
  • GAO Meng-xu ,
  • YU Ye-xiao ,
  • PENG Si-yao ,
  • JIN Guan-ping
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  • Anhui Key Lab of Controllable Chemical Reaction & Material Chemical Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei 230009, Anhui, China

Received date: 2017-07-27

  Revised date: 2017-09-12

  Online published: 2022-01-07

Supported by

National Natural Science Foundation of China (NSFC, No. U140710231) and National College students' innovative training program project (No. 201710359028).

摘要

本文采用电化学方法,制备了一种便于回收和分离的柔性锌镍/铝层状双羟基/碳纤维(ZnNi/Al-LDHs/CFs) 复合材料. 采用X 射线衍射、红外光谱、场发射扫描电镜、电感耦合等离子体原子发射光谱和电化学阻抗光谱技术表征了ZnNi/Al-LDHs/CFs 复合材料的结构、形貌和光电催化性能. 与单独使用Zn/Al-LDHs/CFs 作为光催化剂或Ni/Al-LDHs/CFs 作为电催化剂相比较,ZnNi/Al-LDHs/CFs 复合材料显示了良好的光-电双功能催化特性,既可被用作乙醇和甲醇氧化的电催化剂,也可光电协同催化 26-二氯苯酚降解.

 

本文引用格式

田晶晶 , 陈涛 , 包星辰 , 高梦旭 , 于业笑 , 彭思遥 , 晋冠平 . 柔性ZnNi/Al-LDHs/碳纤维复合材料的制备及光-电催化特性[J]. 电化学, 2018 , 24(4) : 392 -400 . DOI: 10.13208/j.electrochem.170726

Abstract

In this work, a promising flexible composite consisting of zinc (Zn), nickel (Ni) and aluminum (Al) layered double hydroxide coated carbon fibers (ZnNi/Al-LDHs/CFs) was prepared by electrochemical method with convenient recovery and separation. The structures, morphologies, and photo-electro catalytic properties of ZnNi/Al-LDHs/CFs were characterized by X-ray diffraction, infrared spectroscopy, field emission scanning electron microscopy, inductively coupled plasma atomic emission spectrometry and electrochemical impedance spectroscopy techniques. The excellent photo-electro bifunctional catalytic properties were obtained with the ZnNi/Al-LDHs/CFs composite as compared to that of Zn/Al-LDHs/CFs (photo catalyst) or Ni/Al-LDHs/CFs (electrocatalyst) alone, which could be used in the electro-catalytic oxidations of methanol and ethanol, as well as the photo-electro synergistically catalytic degradation of 2,6-dichlorophenol.

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