欢迎访问《电化学(中英文)》期刊官方网站,今天是
研究论文

基于碳复合Fe3O4纳米粒子的过氧化氢电化学传感器研究

  • 张思宇 ,
  • 王会娟 ,
  • 李书芳 ,
  • 屈建莹
展开
  • 河南大学化学化工学院环境与分析科学研究所,河南 开封 475004

收稿日期: 2017-05-06

  修回日期: 2017-09-09

  网络出版日期: 2017-09-17

基金资助

河南省高校科技创新团队支持计划(No. 15IRTSTHN019)资助

Carbon Composite Fe3O4 Nanoparticles Based Electrochemical Sensor for Hydrogen Peroxide Detection

  • ZHANG Si-yu ,
  • WANG Hui-juan ,
  • LI Shu-fang ,
  • QU Jian-ying
Expand
  • Institute of Environmental and Analytical Sciences, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China

Received date: 2017-05-06

  Revised date: 2017-09-09

  Online published: 2017-09-17

摘要

本文以碳纳米粒子复合Fe3O4磁性纳米粒子构建新型过氧化氢电化学传感器,该传感器对过氧化氢有良好的电催化性能,过氧化氢浓度在1.00×10-6 ~ 1.00×10-3 mol·L-1范围内与其氧化峰电流之间呈良好线性关系(R = 0.9980),检出限为6.60×10-7 mol·L-1. 该传感器具有良好的抗干扰能力、较高的重现性和稳定性.

本文引用格式

张思宇 , 王会娟 , 李书芳 , 屈建莹 . 基于碳复合Fe3O4纳米粒子的过氧化氢电化学传感器研究[J]. 电化学, 2018 , 24(3) : 279 -284 . DOI: 10.13208/j.electrochem.170506

Abstract

In this work, a novel hydrogen peroxide electrochemical sensor was constructed with ferroferric oxide (Fe3O4) magnetic nanoparticles, which demonstrated good electrocatalytic activity for hydrogen peroxide. There existed a good linear relationship between the concentration of hydrogen peroxide and the oxidation peak current in the range of 1.00 × 10-6 ~ 1.00 × 10-3 mol·L-1 (R = 0.9980) with the detection limit of 6.60 × 10-7 mol·L-1. The sensor exhibited good anti-interference ability, high reproducibility and stability.

参考文献

[1]  Giorgio M, Trinei M, Migliaccio E, et al. Hydrogen peroxide: a metabolic by-product or a common mediator of ageing signals?[J]. Nature Reviews Molecular Cell Biology, 2007, 8(9): 722-728.
[2]  Zhang R Z, Chen W. Recent advances in graphene-based nanomaterials for fabricating electrochemical hydrogen peroxide sensors[J]. Biosensors and Bioelectronics, 2017, 89(S1): 249-268.
[3]  Ge S G, Liu W Y, Liu H Y, et al. Colorimetric detection of the flux of hydrogen peroxide released from living cells based on the high peroxidase-like catalytic performance of porous PtPd nanorods[J]. Biosensors and Bioelectronics, 2015, 71: 456-462.
[4]  Zheng L Z(郑龙珍), Li Y D(李引弟), Xiong L Y(熊乐艳), et al. Graphene-polydopamine nanocomposite preparation of hydrogen peroxide biosensor[J]. Chinese Journal of Analytical Chemistry (分析化学研究报告), 2012, 1(40): 72-76.
[5]  Shi Y, Su P, Wang Y Y, et al. Fe3O4 peroxidase mimetics as a general strategy for the fluorescent detection of H2O2-involved systems[J]. Talanta, 2014, 130: 259-264.
[6]  Yuan K F, Ni Y H, Zhang L. Facile hydrothermal synthesis of polyhedral Fe3O4 nanocrystals, influencing factors and application in the electrochemical detection of H2O2[J]. Journal of Alloys and Compounds, 2012, 532: 10-15.
[7]  Liu Y, Zhou J, Gong J, et al. The investigation of electrochemical properties for Fe3O4@Pt nanocomposites and an enhancement sensing for nitrite[J]. Electrochimica Acta, 2013, 111: 876-887.
[8] Peng H P, Liang R P, Zhang L, et al. Facile preparation of novel core-shell enzyme-Au-polydopamine-Fe3O4 magnetic bionanoparticles for glucose sensor[J]. Biosensors and Bioelectronics, 2013, 42: 293-299.
[9]  Zhang S, Liu X Y, Huang N, et al. Sensitive detection of hydrogen peroxide and nitrite based on silver/carbon nanocomposite synthesized by carbon dots as reductant via one step method[J]. Electrochimica Acta, 2016, 211: 36-43.
[10]  Liu W(刘文), Wei Z P(魏志鹏), Zheng L Z(郑龙珍). Research progress of the catalytic property of Fe3O4 magnetic nanoparticles[J]. Chinese Journal of Spectroscopy Laboratory(光谱实验室), 2012, 29(4): 1956-1959.
[11]  Liu H, Ye T, Mao C. Fluorescent carbon nanoparticles derived from candle soot[J]. Angewandte Chemie International Edition, 2007, 46(34): 6473-6475.
[12]  Wang S S(王珊珊), Mi W Q(米渭清), Zhu H(朱红), et al. Synthesis of carbon by one step microwave method and its fluorescence properties[J]. Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2012, 32(10): 2710-2713.
[13]  Fang Y, Guo S, Li D, et al. Easy synthesis and imaging applications of cross-linked green fluorescent hollow carbon nanoparticles[J]. ACS Nano, 2011, 6(1): 400-409.
[14]  Li H, Li F, Wang G, et al. One-step synthesis of fluorescent carbon nanoparticles for degradation of naphthol green under visible light[J]. Journal of Luminescence, 2014, 156: 36-40.
[15]  Qu S N, Wang X Y, Lu Q P, et al. A biocompatible fluorescent ink based on water-soluble luminescent carbon nanodots[J]. Angewandte Chemie-International Edition, 2012, 51(49): 12215-12218.
[16]  Cao L, Sahu S, Anilkumar P, et al. Carbon nanoparticles as visible-light photocatalysts for efficient CO2 conversion and beyond[J]. Journal of the American Chemical Society, 2011, 133(13): 4754-4757.
[17]  Liu J(刘杰), Wang S L(王树林), Cui T Y(崔体运), et al. Preparation and characterization of Fe3O4 magnetic nanoparticles[C]//颗粒学前沿问题研讨会暨第九届全国颗粒制备与处理研讨会,中国颗粒学会颗粒制备与处理专业委员会,中国,威海,2009: 179-181.
[18]  He Z, Gudavarthy R V, Koza J A, et al. Room-temperature electrochemical reduction of epitaxial magnetitefilms to epitaxial iron films[J]. Journal of the American Chemical Society, 2011, 133(32): 12358-12361.
[19]  Zhang Z X, Zhu H, Wang X L, et al. Sensitive electrochemical sensor for hydrogen peroxide using Fe3O4 magnetic nanoparticles as a mimic for peroxidase[J]. Micro-
chimica Acta, 2011, 174(1/2): 183-189.
[20]  Zhang L, Zhou N J, Wang B, et al. Fabrication of Fe3O4/PAH/PSS@Pd core-shell microspheres by layer-by-layer assembly and application in catalysis[J]. Journal of Colloid and Interface Science, 2014, 421: 1-5.
[21]  Yu C M, Wang Y D, Wang L, et al. Nanostructured bio-ensors built with layer-by-layer electrostatic assembly of hemoglobin and Fe3O4@Pt nanoparticles[J]. Colloids and Surfaces B: Biointerfaces, 2013, 103: 231-237.
[22]  Wei H, Wang E. Fe3O4 magnetic nanoparticles as peroxidase mimetics and their applications in H2O2 and glucose detection[J]. Analytical Chemistry, 2008, 80(6): 2250-2254.
[23]  Gao L Z, Zhuang J, Nie L, et al. Intrinsic peroxidase-like activity of ferromagnetic nanoparticles[J]. Nature Nanotechnology, 2007, 2(9): 577-583.
[24]  Ma M, Xie J, Zhang Y, et al. Fe3O4@Pt nanoparticles with enhanced peroxidase-like catalytic activity[J]. Matericals Letters, 2013, 105: 36-39.
[25]  Dong Y(董莹), Wang Y(王勇), Xing H H(邢欢欢), et al. Au/Fe3O4/chitosan nanometer compound detecting NO2- electricity sensor[J]. Journal of Electrochemistry(电化学), 2015, 2(21): 85-90.
[26]  Yuan K F, Ni Y H, Zhang L. Facile hydrothermal synthesis of polyhedral Fe3O4 nanocrystals, influencing factors and application in the electrochemical detection of H2O2[J]. Journal of Alloys and Compounds, 2012, 532: 10-15.
[27]  Zhang L H, Zhai Y M, Gao N, et al. Sensing H2O2 with layer-by-layer assembled Fe3O4-PDDA nanocomposite film[J]. Electrochemistry Communications, 2008, 10(10): 1524-1526.
[28]  Liu D, Guo Q H, Zhang X P, et al. PdCo alloy nanoparticle-embedded carbon nanofiber for ultrasensitive nonenzymatic detection of hydrogen peroxide and nitrite[J]. Journal of Colloid and Interface Science, 2015, 450: 168-173.
[29]  Qu J Y, Lou T F, Kang S P, et al. Preparation of poly-(p-aminobenzoic acid)/multiwall carbon nanotubes composite film modified glassy carbon electrode and application to detect catechol and hydroquinone simultaneously[J]. Electrochemistry, 2013, 81(2): 82-85.

文章导航

/