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研究论文

基于碳复合Fe3O4纳米粒子的过氧化氢电化学传感器研究

  • 张思宇 ,
  • 王会娟 ,
  • 李书芳 ,
  • 屈建莹
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  • 河南大学化学化工学院环境与分析科学研究所,河南 开封 475004

收稿日期: 2017-05-06

  修回日期: 2017-09-09

  网络出版日期: 2017-09-17

基金资助

河南省高校科技创新团队支持计划(No. 15IRTSTHN019)资助

Carbon Composite Fe3O4 Nanoparticles Based Electrochemical Sensor for Hydrogen Peroxide Detection

  • ZHANG Si-yu ,
  • WANG Hui-juan ,
  • LI Shu-fang ,
  • QU Jian-ying
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  • Institute of Environmental and Analytical Sciences, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China

Received date: 2017-05-06

  Revised date: 2017-09-09

  Online published: 2017-09-17

摘要

本文以碳纳米粒子复合Fe3O4磁性纳米粒子构建新型过氧化氢电化学传感器,该传感器对过氧化氢有良好的电催化性能,过氧化氢浓度在1.00×10-6 ~ 1.00×10-3 mol·L-1范围内与其氧化峰电流之间呈良好线性关系(R = 0.9980),检出限为6.60×10-7 mol·L-1. 该传感器具有良好的抗干扰能力、较高的重现性和稳定性.

本文引用格式

张思宇 , 王会娟 , 李书芳 , 屈建莹 . 基于碳复合Fe3O4纳米粒子的过氧化氢电化学传感器研究[J]. 电化学, 2018 , 24(3) : 279 -284 . DOI: 10.13208/j.electrochem.170506

Abstract

In this work, a novel hydrogen peroxide electrochemical sensor was constructed with ferroferric oxide (Fe3O4) magnetic nanoparticles, which demonstrated good electrocatalytic activity for hydrogen peroxide. There existed a good linear relationship between the concentration of hydrogen peroxide and the oxidation peak current in the range of 1.00 × 10-6 ~ 1.00 × 10-3 mol·L-1 (R = 0.9980) with the detection limit of 6.60 × 10-7 mol·L-1. The sensor exhibited good anti-interference ability, high reproducibility and stability.
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