硫化镍/三维网络石墨烯复合材料制备及其在高性能超级电容器的应用研究
收稿日期: 2016-12-06
修回日期: 2017-01-15
网络出版日期: 2017-02-09
基金资助
国家自然科学基金项目（51572184，51372160）资助
Novel Composites between Nano-Structured Nickel Sulfides and Three-Dimensional Graphene for High Performance Supercapacitors
Received date: 2016-12-06
Revised date: 2017-01-15
Online published: 2017-02-09
Supported by
This work was supported by the National Natural Science Foundation of China (Grant No. 51372160 and 51172152).
本文在泡沫镍上生长三维网络状结构的石墨烯（3DG），以此为模板合成石墨烯复合电极并将其应用于超级电容器. 采用一步水热法在3DG上合成得到Ni3S2纳米棒结构（Ni3S2/3DG）. 通过TEM、XRD、SEM和拉曼光谱等手段表征对Ni3S2/3DG复合材料的形态与结构进行表征. 电化学测试表明，Ni3S2/3DG复合材料具有高的比电容（在扫速为5 mV·s-1下，具有1825.3 F·g-1的比容量）和放电电容（在电流密度10 mA下电容高达516.7 F·g-1）. 此外，在电流密度20 mA下具有良好的循环性能（循环1000周后仍能保留约100%的初始电容）. 本工作为得到高能量密度和良好的长期稳定性的复合材料提供了参考.
王晓敏 , 窦湟琳 , 田 真 , 张久俊 . 硫化镍/三维网络石墨烯复合材料制备及其在高性能超级电容器的应用研究[J]. 电化学, 2017 , 23(2) : 217 -225 . DOI: 10.13208/j.electrochem.161246
In this paper, a three-dimensional graphene (3DG) network grown on nickel foam was employed as a template for synthesizing graphene-based composite materials of supercapacitor electrode. The composites (crystal Ni3S2 nanorods on the surface of 3DG (abbreviated as Ni3S2/3DG)) were obtained through a one-step hydrothermal reaction. The morphological and structural evolution of the Ni3S2/3DG composites were investigated by SEM, TEM, XRD and Raman spectroscopy. Detailed electrochemical characterization showed that the Ni3S2/3DG-coated electrodes exhibited both a specific capacitance as high as 1825 F·g-1 at 5 mV·s-1 and a discharge capacitance as high as 517 F·g-1 at 10 mA. Remarkably, a high cycling performance (~ 100% capacitance retention after 1000 cycles) is achieved at a current density of 20 mA.
[1] Zhang C, He X J, Li G R, Reduced graphene oxide (RGO) hollow network cages for high-performance electrochemical energy storage[J]. Journal of Electrochemistry, 2016, 22(3): 278-287.
[2] Zhong C, Deng Y D, Hu W B, et al. A review of electrolyte materials and compositions for electrochemical supercapacitors[J]. Chemical Society Reviews, 2015, 44: 7484-7539.
[3] Su X, Yu L, Cheng G, et al. Controllable hydrothermal synthesis of Cu-doped δ-MnO2 films with different morphologies for energy storage and conversion using supercapacitors[J]. Applied Energy, 2014, 134: 439-445.
[4] Ambrosi A, Chua C K, Bonanni A, Pumera M. Electrochemistry of graphene and related materials. Chemical Reviews[J]. 2014, 114(14): 7150-7188.
[5] Ghosh D, Das C K. Hydrothermal growth of hierarchical Ni3S2 and Co3S4 on a reduced graphene oxide hydrogel@Ni foam: a high-energy-density aqueous asymmetric supercapacitor[J]. ACS Applied Materials & Interfaces, 2015, 7: 1122-1131.
[6] Zhao B, Jiang L, Yuen M H, et al. Electrochemical syntheses of graphene and composites[J]. Journal of Electrochemistry, 2016, 22(1): 1-19.
[7] Banerjee P C, Lobo D E, Middag R, et al. Electrochemical capacitance of Ni-doped metal organic framework and reduced graphene oxide composites: more than the sum of its parts [J]. ACS Applied Materials & Interfaces, 2015, 7(6): 3655-3664.
[8] Liu Y, Wang R, Yan X. Synergistic effect between ultra-small nickel hydroxide nanoparticles and reduced graphene oxide sheets for the application in high-performance asymmetric supercapacitor[J]. Scientific Reports, 2015, 5: 11095.
[9] Jiang W, Yu D, Zhang Q, et al. Ternary hybrids of amorphous nickel hydroxide-carbon nanotube-conducting polymer for supercapacitors with high energy density, excellent rate capability, and long cycle life[J]. Advanced Functional Materials, 2015, 25(7): 1063-1073.
[10] Yang B, Yu L, Liu Q, et al. The growth and assembly of the multidimensional hierarchical Ni3S2 for aqueous asymmetric supercapacitors[J]. CrystEngComm, 2015, 17: 4495-4501.
[11] Salunkhe R R, Lin J, Malgras V, et al. Large-scale synthesis of coaxial carbon nanotube/Ni(OH)2 composites for asymmetric supercapacitor application[J]. Nano Energy, 2015, 11: 211-218.
[12]
[13] Li H, Yang X W, Wang X M, et al. A dual-spatially-confined reservoir by packing micropores within dense graphene for long-life lithium/sulfur batteries[J]. Nanoscale, 2016, 8: 2395-2402.
[14] Zhang Z, Wang Q, Zhao C, et al. One-step hydrothermal synthesis of 3D petal-like Co9S8/RGO/Ni3S2 composite on nickel foam for high-performance supercapacitors[J]. ACS Applied Materials & Interfaces, 2015, 7(8): 4861-4618.
[15] Ramachandran R, Saranya M, Velmurugan V, et al. Effect of reducing agent on graphene synthesis and its influence on charge storage towards supercapacitor applications [J]. Applied Energy, 2015, 153: 22-31.
[16] Zhang Z, Liu X, Qi X, et al. Hydrothermal synthesis of Ni3S2/graphene electrode and its application in a supercapacitor[J]. RSC Advances, 2014, 4: 37278.
[17] Xu Y, Huang X, Lin Z, et al. One-step strategy to graphene/Ni(OH)2 composite hydrogels as advanced three-dimensional supercapacitor electrode materials[J]. Nano Research, 2012, 6(1): 65-76.
[18] Yan H, Bai J, Wang B, et al. Electrochemical reduction approach-based 3D graphene/Ni(OH)2 electrode for high-performance supercapacitors[J]. Electrochimica Acta, 2015, 154: 9-16.
[19] Mao S, Lu G, Chen J. Three-dimensional graphene-based composites for energy applications[J]. Nanoscale, 2015, 7: 6924-6943.
[20]Philip M R, Narayanan T N, Praveen Kumar M, et al. Self-protected nickel–graphene hybrid low density 3D scaffolds[J]. Journal of Materials Chemistry A, 2014, 45: 19488-19494.
[21] Zhang Z, Huang Z, Ren L, et al. One-pot synthesis of hierarchically nanostructured Ni3S2 dendrites as active materials for supercapacitors[J]. Electrochimica Acta, 2014, 149: 316-323.
[22] Yu W, Lin W, Shao X, et al. High performance supercapacitor based on Ni3S2/carbon nanofibers and carbon nanofibers electrodes derived from bacterial cellulose[J]. Journal of Power Sources, 2014, 272: 137-
[23] Zhou W,
[24] Li M, Tang Z, Leng M, et al. Flexible solid-state supercapacitor based on graphene-based hybrid films[J]. Advanced Functional Materials, 2014, 24(47): 7495-7502.
[25] Wang Y, Wu G C, Wang Y Z, et al. Effect of water content on the ethanol electro-oxidation activity of Pt-Sn/graphene catalysts prepared by the polyalcohol method[J]. Electrochimica Acta, 2014, 130: 135-140.
[26] Li G, Xu C. Hydrothermal synthesis of 3D NixCo1−xS2 particles/graphene composite hydrogels for high performance supercapacitors[J]. Carbon, 2015, 90: 44-52.
Nguyen V H, Lamiel C, Shim J J. Hierarchical mesoporous graphene@Ni-Co-S arrays on nickel foam for high-performance supercapacitors[J]. Electrochimica Acta, 2015, 161: 351-357
[27] Huo H, Zhao Y, Xu C. 3D Ni3S2 nanosheet arrays supported on Ni foam for high-performance supercapacitor and non-enzymatic glucose detection[J]. Journal of Materials Chemistry A, 2014, 36: 15111-15117.
[3] Su X, Yu L, Cheng G, et al. Controllable hydrothermal synthesis of Cu-doped δ-MnO2 films with different morphologies for energy storage and conversion using supercapacitors[J]. Applied Energy, 2014, 134: 439-445.
[4] Ambrosi A, Chua C K, Bonanni A, Pumera M. Electrochemistry of graphene and related materials. Chemical Reviews[J]. 2014, 114(14): 7150-7188.
[5] Ghosh D, Das C K. Hydrothermal growth of hierarchical Ni3S2 and Co3S4 on a reduced graphene oxide hydrogel@Ni foam: a high-energy-density aqueous asymmetric supercapacitor[J]. ACS Applied Materials & Interfaces, 2015, 7: 1122-1131.
[6] Zhao B, Jiang L, Yuen M H, et al. Electrochemical syntheses of graphene and composites[J]. Journal of Electrochemistry, 2016, 22(1): 1-19.
[7] Banerjee P C, Lobo D E, Middag R, et al. Electrochemical capacitance of Ni-doped metal organic framework and reduced graphene oxide composites: more than the sum of its parts [J]. ACS Applied Materials & Interfaces, 2015, 7(6): 3655-3664.
[8] Liu Y, Wang R, Yan X. Synergistic effect between ultra-small nickel hydroxide nanoparticles and reduced graphene oxide sheets for the application in high-performance asymmetric supercapacitor[J]. Scientific Reports, 2015, 5: 11095.
[9] Jiang W, Yu D, Zhang Q, et al. Ternary hybrids of amorphous nickel hydroxide-carbon nanotube-conducting polymer for supercapacitors with high energy density, excellent rate capability, and long cycle life[J]. Advanced Functional Materials, 2015, 25(7): 1063-1073.
[10] Yang B, Yu L, Liu Q, et al. The growth and assembly of the multidimensional hierarchical Ni3S2 for aqueous asymmetric supercapacitors[J]. CrystEngComm, 2015, 17: 4495-4501.
[11] Salunkhe R R, Lin J, Malgras V, et al. Large-scale synthesis of coaxial carbon nanotube/Ni(OH)2 composites for asymmetric supercapacitor application[J]. Nano Energy, 2015, 11: 211-218.
[12]
[13] Li H, Yang X W, Wang X M, et al. A dual-spatially-confined reservoir by packing micropores within dense graphene for long-life lithium/sulfur batteries[J]. Nanoscale, 2016, 8: 2395-2402.
[14] Zhang Z, Wang Q, Zhao C, et al. One-step hydrothermal synthesis of 3D petal-like Co9S8/RGO/Ni3S2 composite on nickel foam for high-performance supercapacitors[J]. ACS Applied Materials & Interfaces, 2015, 7(8): 4861-4618.
[15] Ramachandran R, Saranya M, Velmurugan V, et al. Effect of reducing agent on graphene synthesis and its influence on charge storage towards supercapacitor applications [J]. Applied Energy, 2015, 153: 22-31.
[16] Zhang Z, Liu X, Qi X, et al. Hydrothermal synthesis of Ni3S2/graphene electrode and its application in a supercapacitor[J]. RSC Advances, 2014, 4: 37278.
[17] Xu Y, Huang X, Lin Z, et al. One-step strategy to graphene/Ni(OH)2 composite hydrogels as advanced three-dimensional supercapacitor electrode materials[J]. Nano Research, 2012, 6(1): 65-76.
[18] Yan H, Bai J, Wang B, et al. Electrochemical reduction approach-based 3D graphene/Ni(OH)2 electrode for high-performance supercapacitors[J]. Electrochimica Acta, 2015, 154: 9-16.
[19] Mao S, Lu G, Chen J. Three-dimensional graphene-based composites for energy applications[J]. Nanoscale, 2015, 7: 6924-6943.
[20] Philip M R, Narayanan T N, Praveen Kumar M, et al. Self-protected nickel-graphene hybrid low density 3D scaffolds[J]. Journal of Materials Chemistry A, 2014, 45: 19488-19494.
[21] Zhang Z, Huang Z, Ren L, et al. One-pot synthesis of hierarchically nanostructured Ni3S2 dendrites as active materials for supercapacitors[J]. Electrochimica Acta, 2014, 149: 316-323.
[22] Yu W, Lin W, Shao X, et al. High performance supercapacitor based on Ni3S2/carbon nanofibers and carbon nanofibers electrodes derived from bacterial cellulose[J]. Journal of Power Sources, 2014, 272: 137-
[23] Zhou W,
[24] Li M, Tang Z, Leng M, et al. Flexible solid-state supercapacitor based on graphene-based hybrid films[J]. Advanced Functional Materials, 2014, 24(47): 7495-7502.
[25] Wang Y, Wu G C, Wang Y Z, et al. Effect of water content on the ethanol electro-oxidation activity of Pt-Sn/graphene catalysts prepared by the polyalcohol method[J]. Electrochimica Acta, 2014, 130: 135-140.
[26] Li G, Xu C. Hydrothermal synthesis of 3D NixCo1-xS2 particles/graphene composite hydrogels for high performance supercapacitors[J]. Carbon, 2015, 90: 44-52.
[27] Nguyen V H, Lamiel C, Shim J J. Hierarchical mesoporous graphene@Ni-Co-S arrays on nickel foam for high-performance supercapacitors[J]. Electrochimica Acta, 2015, 161: 351-357
[28] Huo H, Zhao Y, Xu C. 3D Ni3S2 nanosheet arrays supported on Ni foam for high-performance supercapacitor and non-enzymatic glucose detection[J]. Journal of Materials Chemistry A, 2014, 36: 15111-15117.
[29] Zhou R, Han C J, Wang X M. Hierarchical MoS2-coated three-dimensional graphene network for enhanced supercapacitor performances[J]. Journal of Power Sources, 2017, 352:99-110.
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