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2016 , Vol. 22 >Issue 6: 561 - 569

DOI: https://doi.org/10.13208/j.electrochem.160563

界面电化学近期研究专辑（厦门大学 毛秉伟教授）

燃料电池电极表界面催化氧还原反应的STM研究进展

  • 蔡镇锋 ,
  • 孙兵 ,
  • 江文杰 ,
  • 陈婷 ,
  • 王栋 ,
  • 万立骏
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  • 1. 中国科学院化学研究所, 中国科学院分子纳米结构与纳米技术重点实验室, 北京 100190; 2. 中国科学院大学, 北京 100049

收稿日期: 2016-06-01

  修回日期: 2016-07-07

  网络出版日期: 2016-07-21

基金资助

国家自然科学基金项目（21233010, 21373236, 21127901, 21573252）资助

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STM Investigation of Oxygen Reduction Reaction on Solid Interface in Fuel Cell

  • CAI Zhen-Feng ,
  • SUN Bing ,
  • JIANG Wen-Jie ,
  • CHEN Ting ,
  • WANG Dong ,
  • WAN Li-Jun
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  • 1. CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China; 2. University of Chinese Academy of Sciences, Beijing 100049, China

Received date: 2016-06-01

  Revised date: 2016-07-07

  Online published: 2016-07-21

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摘要

催化氧还原反应的电催化剂是燃料电池的一个重要组成部分. 从分子尺度研究催化氧还原反应中所涉及的表界面反应机理，不仅有利于深入理解催化机理，更有利于指导人们合理地设计新型的电催化剂. 本文结合近年来国内外的研究工作，概述了通过扫描隧道显微镜研究燃料电池内部催化氧还原反应过程中所涉及的表面形貌变化、单分子结构变化、中间体的观测以及反应产物调控等方面最新进展，并展望了该研究领域的发展趋势.

关键词： 燃料电池; 氧还原反应; 扫描隧道显微术

本文引用格式

蔡镇锋 , 孙兵 , 江文杰 , 陈婷 , 王栋 , 万立骏 . 燃料电池电极表界面催化氧还原反应的STM研究进展[J]. 电化学, 2016 , 22(6) : 561 -569 . DOI: 10.13208/j.electrochem.160563

Abstract

An electrocatalyst for oxygen reduction reaction (ORR) is an important component for fuel cells. An investigation at interfacial electrochemical reactions toward ORR at a molecular scale benefits mechanistic understanding as well as rational design of catalysts. Scanning tunneling microscopy (STM) has been proven to be a powerful tool to monitor chemical reactions and to provide in-situ information about the interfacial electrochemical reactions at a molecular level. This review summarizes the recent STM studies in monitoring the interface processes such as morphological changes, molecular changes, reaction intermediates, and oxidation products. The prospects of future development in this field are outlined.

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