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光电化学及新型太阳能电池近期研究专辑(厦门大学林昌健教授&中国科学院化学研究所李永舫院士主编)

卟啉及其光电化学研究进展

  • 刘双双 ,
  • 鲁建峰 ,
  • 王鸣魁
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  • 1.华中科技大学,武汉光电国家实验室,武汉,珞喻路1037号,430074;2. Materials Science and Engineering, Monash University, Clayton, 3800, Victoria, Australia

收稿日期: 2016-02-23

  修回日期: 2016-03-09

  网络出版日期: 2016-03-17

基金资助

国家重点基础研究发展计划(NO. 2014CB643506),脉冲强磁场国家重大科技基础设施开发共享课题(No.2015KF18)资助

Prospects of D-π-A structured porphyrins and their photoelectrochemical application

  • LIU Shuang-shuang ,
  • Lu Jian-feng ,
  • Wang Ming-kui
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  • 1.Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan , 430074,Hubei,China;2. Materials Science and Engineering, Monash University, Clayton, 3800, Victoria, Australia

Received date: 2016-02-23

  Revised date: 2016-03-09

  Online published: 2016-03-17

摘要

卟啉及金属卟啉在自然界中广泛存在,其光学、电化学等特性可通过分子结构中多个反应位点进行调控. 随着全球能源环境问题日益凸显,卟啉在太阳能电池、光催化制氢领域的研究成为热点. 本文简介了作者课题组近年来通过国内外合作开展的D-π-A结构卟啉分子结构改性及其对光电化学性质和器件光伏特性影响的进展,并对未来卟啉光电化学研究的发展进行了简要的探讨.

本文引用格式

刘双双 , 鲁建峰 , 王鸣魁 . 卟啉及其光电化学研究进展[J]. 电化学, 2016 , 22(4) : 340 -355 . DOI: 10.13208/j.electrochem.160143

Abstract

Porphyrins and their metalloderivatives are a class of compounds exhibiting a wide variety of interesting and highly useful properties, such as chlorophyll. Porphyrins are particularly interesting in photoelectrochemical applications due to their structural similarity to chlorophylls in natural photosynthetic systems, as well as their strong and tunable absorption properties. Recently, various porphyrins have been extensively studied for their applications in solar cells, photocatalytic hydrogen production, optical information storage and others. This review will focus on the unique physical and chemical properties of D-π-A structured porphyrins, and their photovoltaic performances in dye-sensitized solar cells. A brief discussion in the future development of porphyrins is presented.

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