包覆型非贵金属氧还原催化剂的研究进展
收稿日期: 2016-01-05
修回日期: 2016-02-29
网络出版日期: 2016-04-28
基金资助
科技部973项目(No. 2012CB215500)、国家自然科学基金项目(No. 21373199,No. 21433003)、中国科学院先导专项(No. XDA09030104)、吉林省科技发展项目(No. 20130206068GX,No. 20140203012SF,No. 20102204)和吉林省自然科学基金项目(No. 20150101066JC)资助
Recent Progress in Non-Precious Metal Oxygen Reduction Reaction Catalysts with an Encapsulation Structure
Received date: 2016-01-05
Revised date: 2016-02-29
Online published: 2016-04-28
肖梅玲 , 祝建兵 , 刘长鹏 , 葛君杰 , 邢 巍 . 包覆型非贵金属氧还原催化剂的研究进展[J]. 电化学, 2016 , 22(2) : 101 -112 . DOI: 10.13208/j.electrochem.151152
Platinum-based materials, the state-of-the-art catalysts for fuel cells, suffer from prohibitive costs, limited resources and insufficient durability. Accordingly, tremendous efforts were made in searching for efficient, durable and inexpensive alternatives to precious-metal electrocatalysts for the oxygen reduction reaction (ORR). Transition-metals (Fe, Co)/nitrogen co-doped hybrids, heteroatom (N, P, S, F, et al) doped carbons and composites with transition-metals encapsulated in graphitic layers are reported as the most efficient non-precious metal ORR catalysts. Among the various non-precious metal ORR catalysts, transition-metals encased in graphitic layer catalysts are a novel type of catalysts for ORR with high activity and durability, and thus, the in-depth researches are highly desirable. Here, we present the recent research progress in transition-metals encased catalysts from the aspects of synthesis, activity and catalytic mechanism, in an effort to promote the developments of these catalysts.
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