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燃料电池电化学催化与催化剂近期研究专辑(重庆大学 魏子栋教授主编)

钼基析氢反应电催化剂的研究进展

  • 吴则星 ,
  • 王 杰 ,
  • 郭军坡 ,
  • 朱 静 ,
  • 王得丽
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  • 华中科技大学化学与化工学院,能量转换与存储材料化学教育部重点实验室,材料化学与服役失效湖北省重点实验室,湖北 武汉 430074

收稿日期: 2015-12-10

  修回日期: 2016-01-27

  网络出版日期: 2016-04-28

基金资助

国家自然科学基金项目(No. 21306060,No. 21573083)、教育部新世纪优秀人才支持计划(No. NCET 130237)资助

Recent Progresses in Molybdenum-Based Electrocatalysts for the Hydrogen Evolution Reaction

  • WU Ze-xing ,
  • Wang Jie ,
  • Guo Jun-po ,
  • Zhu Jing ,
  • Wang De-li
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  • Key Laboratory of Material Chemistry for Energy Conversion and Storage (Huazhong University of Science and Technology), Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

Received date: 2015-12-10

  Revised date: 2016-01-27

  Online published: 2016-04-28

摘要

电催化析氢反应作为一种绿色、可持续的制备氢气方法,受到了广泛关注. 近年来,非贵金属析氢催化剂以其低成本和相对高的催化活性取得了较快的研究进展,其中,钼基纳米催化剂目前已成为电催化析氢中最受关注的研究热点之一. 本文综述了钼基碳化物、磷化物、氮化物以及硫化物在电催化析氢反应中的催化机理和研究进展,分析了提高析氢催化活性的方法,并对钼基非贵金属催化剂的发展趋势进行了展望.

本文引用格式

吴则星 , 王 杰 , 郭军坡 , 朱 静 , 王得丽 . 钼基析氢反应电催化剂的研究进展[J]. 电化学, 2016 , 22(2) : 192 -204 . DOI: 10.13208/j.electrochem.151143

Abstract

Electrochemical catalytic production of hydrogen has been considered as a promising and sustainable strategy for clean and renewable energy technologies. Molybdenum-based non noble metal catalysts for the hydrogen evolution reaction have attracted extensive attention due to its effective catalytic performance. In this review, the recent progresses in molybdenum-carbide, phosphide, nitride and sulfide electrocatalysts are presented. In addition, the strategies to improve the catalytic performance are analyzed and the prospects for the future development trends are expected.

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