Co3(HCOO)6@rGO as a Promising Anode for Lithium Ion Batteries

doi:10.13208/j.electrochem.170412

Abstract

Abstract: Metal–organic framework(MOF) is a kind of novel electrode materials for lithium ion batteries. Here, a composite material Co₃(HCOO)₆@rGO was synthesized for the first time by in situ loading of Co₃(HCOO)₆ on rGO (reduced oxide graphene) through a solution chemistry method. As an anode material for lithium ion batteries, it exhibited an excellent cycle stability as well as a large reversible capacity of 926 mAh·g^-1 at a current density of 500 mA·g^-1 after 100 cycles within the voltage range of 0.02 ~ 3.0 V vs. Li/Li⁺with a good rate capability. The results of cyclic voltammetry and XPS measurements revealed that both Co²⁺ and formate ions in Co₃(HCOO)₆@rGO uderwent reversible electrochemical reactions during the charge and discharge process. Compared with Co₃(HCOO)₆ synthesized through the same method, it was found that rGO could activate the electrochemical reaction of formate ion, which improved the Co₃(HCOO)₆ rate performance.A new route was demonstrated through this work to enhance the specific capacity and rate capability of MOFs by introducing rGO.

Key words: Co₃(HCOO)₆@rGO; Co₃(HCOO)₆, formate ion, anode, lithium ion batteries

CLC Number:

O646

JIANG Heng, FAN Jing-min, ZHENG Ming-sen, DONG Quan-feng. Co₃(HCOO)₆@rGO as a Promising Anode for Lithium Ion Batteries[J]. Journal of Electrochemistry, 2018, 24(3): 207-215.

References

[1] Armand M, Tarascon J M. Building better batteries[J]. Naure, 2008, 451(7179): 652-657.
[2] Chu D B（褚道葆）, Li J（李建）, Yuan X M(袁希梅), et al. Tin-based alloy anode materials for lithium ion batteries[J]. Progress in Chemistry(化学进展), 2012, 27(8): 1466-1476.
[3] Huang X L, Wang R Z, Xu D, et al. Homogeneous CoO on graphene for binder-free and ultralong-life lithium ion batteries[J]. Advanced Functional Materials, 2013, 23(35): 4345-4353.
[4] Armand M, Grugeon S, Vezin H, et al. Conjugated dicarboxylate anodes for Li-ion batteries[J]. Nature Materials, 2009, 8(2): 120-125.
[5] Wang S, Wang L, Zhang K, et al. Organic Li₄C₈H₂O₆ nano-sheets for lithium-ion batteries[J]. Nano Letters, 2013, 13(9): 4404-4409.
[6] Long J R, Yaghi O M. The pervasive chemistry of metal-organic frameworks[J]. Chemical Society Reviews, 2009, 38(5): 1213-1214.
[7] Ke F S, Wu Y S, Deng H. Metal-organic frameworks for lithium ion batteries and supercapacitors[J]. Journal of Solid State Chemistry, 2015, 223(S1): 109-121.
[8] Liu Y, Wang Z U, Zhou H C. Recent advances in carbon dioxide capture with metal-organic frameworks[J]. Greenhouse Gases: Science and Technology, 2012, 2(4): 239-259.
[9] Wang Z, Chen G, Ding K. Self-supported catalysts[J]. Chemical Reviews, 2009, 109(2): 322-359.
[10] Vallet-Regí M, Balas F, Arcos D. Mesoporous materials for drug delivery[J]. Angewandte Chemie International Edition, 2007, 46(40): 7548-7558.
[11] Motokawa N, Matsunaga S, Takaishi S, et al. Reversible magnetism between an antiferromagnet and a ferromagnet related to solvation/desolvation in a robust layered [Ru₂]₂TCNQ charge-transfer system[J]. Journal of the American Chemical Society, 2010, 132(34): 11943-11951.
[12] Liu K, You H P, Zheng Y H, et al. Facile and rapid fabrication of metal-organic framework nanobelts and colortunable photoluminescence properties[J]. Journal of Materials Chemistry, 2010, 20(16): 3272-3279.
[13] Li X, Cheng F, Zhang S, et al. Shape-controlled synthesis and lithium-storage study of metal-organic frameworks Zn₄O(1,3,5-benzenetribenzoate)₂[J]. Journal of Power Sources, 2006, 160(1): 542-547.
[14] Gou L, Hao L M, Shi Y X, et al. One-pot synthesis of a metal-organic framework as an anode for Li-ion batteries with improved capacity and cycling stability[J]. Journal of Solid State Chemistry, 2014, 210(1): 121-124.
[15] Su F Y, You C, He Y B, et al. Flexible and planar graphene conductive additives for lithium-ion batteries[J]. Journal of Materials Chemistry, 2010, 20(43): 9644-9650.
[16] Wang Z, Zhang B, Kurmoo M, et al. Synthesis and characterization of a porous magnetic diamond framework, Co₃(HCOO)₆, and its N₂ sorption characteristic[J]. Inorganic Chemistry, 2005, 44(5): 1230-1237.
[17] Guo J C, Liu Q, Wang C S, et al. Interdispersed amorphous mnox-carbon nanocomposites with superior electrochemical performance as lithium-storage material[J]. Advanced Functional Materials, 2012, 22(4): 803-811.
[18] Wang L P, Mou C X, Sun Y, et al. Structure-property of metal organic frameworks calcium terephthalates anodes for lithium-ion batteries[J]. Electrochimica Acta, 2015, 173: 235-241.
[19] Khassin A A, Yurieva T M, Kaichev V V, et al. Metal-support interactions in cobalt-aluminum co-precipitated catalysts: XPS and CO adsorption studies[J]. Journal of Molecular Catalysis A: Chemical, 2001, 175(1/2): 189-204.
[20] Kocijan A, Milošev I, Pihlar B. Cobalt-based alloys for orthopaedic applications studied by electrochemical and XPS analysis[J]. Journal of Materials Science: Materials in Medicine, 2004, 15(6): 643-650.
[21] Fu L, Liu Z M, Liu Y Q, et al. Beaded cobalt oxide nanoparticles along carbon nanotubes: Towards more highly integrated electronic devices[J]. Advanced Materials, 2005, 17(2): 217-221.
[22] Coulter K E, Sault A G. Effects of activation on the surface properties of silica-supported cobalt catalysts[J]. Journal of Catalysis, 1995, 154(1): 56-64.
[23] Yang Z, Xu X, Liang X, et al. MIL-53(Fe)-graphene nanocomposites: Efficient visible-light photocatalysts for the selective oxidation of alcohols[J]. Applied Catalysis B: Environmental, 2016, 198: 112-123.
[24] Sivaprakash S, Majumder S B. Spectroscopic analyses of 0.5Li[Ni_0.8Co_0.15Zr_0.05]O₂-0.5Li[Li_1/3Mn_2/3]O₂ composite cathodes for lithium rechargeable batteries[J]. Solid State Ionics, 2010, 181(15/16): 730-739.
[25] Leroy S, Martinez H, Dedryvère R, et al. Influence of the lithium salt nature over the surface film formation on a graphite electrode in Li-ion batteries: An XPS study[J]. Applied Surface Science, 2007, 253(11): 4895-4905.

Co₃(HCOO)₆@rGO as a Promising Anode for Lithium Ion Batteries

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Shu-Jin Li, Zhi-Kang Cao, Wen-Kai Wang, Xiao-Han Zhang, Xing-De Xiang. Functional Sulfate Electrolytes Enable the Enhanced Cycling Stability of NaTi₂(PO₄)₃/C Anode Material for Aqueous Sodium-Ion Batteries [J]. Journal of Electrochemistry, 2021, 27(6): 605-613.
[2]	Li Zhou, Lie Wu, Zhao-Ming Xue. Preparation and Characterization of Thermoplastic Polyurethane-Based Polymer Electrolyte [J]. Journal of Electrochemistry, 2021, 27(4): 439-448.
[3]	Dylan Siltamaki, Shuai Chen, Farnood Rahmati, Jacek Lipkowski, Ai-Cheng Chen. Synthesis and Electrochemical Study of CuAu Nanodendrites for CO₂ Reduction [J]. Journal of Electrochemistry, 2021, 27(3): 278-290.
[4]	Zhen-Lang Liang, Yao Yang, Hao Li, Li-Ying Liu, Zhi-Cong Shi. Lithium Storage Performance of Hard Carbons Anode Materials Prepared by Different Precursors [J]. Journal of Electrochemistry, 2021, 27(2): 177-184.
[5]	Shou-Xun Hu, Liang Li, Jun-Hao Yang, Liu-Qiang Li, Zhi-Hao Jin. Preparations and Electrocatalytic Ethanol Properties of Palladium Intercalated Hydrotalcite [J]. Journal of Electrochemistry, 2021, 27(1): 100-107.
[6]	Gui-Wei Chen, Zheng-Liang Gong. Study on Li₃BO₃ Interface Modification of Garnet Solid Electrolyte [J]. Journal of Electrochemistry, 2021, 27(1): 76-82.
[7]	DUAN Ming-tao, MENG Yan-shuang, ZHANG Hong-shuai. Preparations and Sodium Storage Properties of Ni₃S₂@CNT Composite [J]. Journal of Electrochemistry, 2020, 26(6): 850-858.
[8]	CHEN Jia-jia, DONG Quan-feng. Research Progress of Key Components in Lithium-Sulfur Batteries [J]. Journal of Electrochemistry, 2020, 26(5): 648-662.
[9]	DENG Bo-wen, YIN Hua-yi, WANG Di-hua. Highly Efficient CO₂ Utilization via Molten Salt CO₂ Capture and Electrochemical Transformation Technology [J]. Journal of Electrochemistry, 2020, 26(5): 628-638.
[10]	CHEN Jia-hui, ZHONG Xiao-bin, HE Chao, WANG Xiao-xiao, XU Qing-chi, LI Jian-feng. Synthesis and Raman Study of Hollow Core-Shell Ni_1.2Co_0.8P@N-C as an Anode Material for Sodium-Ion Batteries [J]. Journal of Electrochemistry, 2020, 26(3): 328-337.
[11]	ZHANG Qing-nuan, ZHANG Fang-fang, LI Hong-xia, YANG Bing-jun, LI Xiao-cheng, YANG Juan. Lithium Storage Performance of High Capacity Material Si@C_PZS in Lithium Ion Batteries [J]. Journal of Electrochemistry, 2020, 26(1): 121-129.
[12]	LANG Shuang-yan, HU Xin-cheng, WEN Rui, WAN Li-jun. In Situ/Operando Visualization of Electrode Processes in Lithium-Sulfur Batteries: A Review [J]. Journal of Electrochemistry, 2019, 25(2): 141-159.
[13]	WANG Fan-fan, LIU Xiao-bin, CHEN Long, CHEN Cheng-cheng, LIU Yong-chang, FAN Li-zhen. Recent Progress in Key Materials for Room-Temperature Sodium-Ion Batteries [J]. Journal of Electrochemistry, 2019, 25(1): 55-76.
[14]	CHEN Jia-hang, YANG Hui-jun, GUO Cheng, WANG Jiu-lin. Current Status and Prospect of Battery Configuration in Li-S System [J]. Journal of Electrochemistry, 2019, 25(1): 3-16.
[15]	YAN Chong, KOU Hua-ri, YAN Bo, LIU Xiao-jing, LI De-jun, LI Xi-fei. Ni/Mn₃O₄/NiMn₂O₄ Double-Shelled Hollow Spheres Embedded into Reduced Graphene Oxide as Advanced Anodes for Sodium-Ion Batteries [J]. Journal of Electrochemistry, 2019, 25(1): 112-121.