分子催化剂电化学活化氮气用于可持续合成氨

韩金秀, 薛皓, 付先彪

Molecular Catalysts for Electrochemical Nitrogen Activation toward Sustainable Ammonia Synthesis

Jin-Xiu Han, Hao Xue, Xian-Biao Fu

Fig. 17. (a) Schematic of a tandem electrocatalytic strategy enabled by coupling the PCET mediator Co(II,NH)+ with molecular NRR catalysts, allowing well-defined N2 reduction at relatively mild applied potentials. (b) A series of molecular NRR catalysts was tested under electrocatalytic conditions in the presence of the Co(II,NH)+ PCET mediator. Reproduced with permission of Ref. [90]. Copyright 2022, Springer Nature.