分子催化剂电化学活化氮气用于可持续合成氨

韩金秀, 薛皓, 付先彪

Molecular Catalysts for Electrochemical Nitrogen Activation toward Sustainable Ammonia Synthesis

Jin-Xiu Han, Hao Xue, Xian-Biao Fu

Fig. 16. In the P3BFe+/Cp*2Co NRR system, anilinium acids tune the balance between NRR and HER by protonating Cp*2Co to form a PCET donor, which then drives N−H bond formation. Reproduced with permission of Ref. [89]. Copyright 2018, American Chemical Society.