分子催化剂电化学活化氮气用于可持续合成氨
Molecular Catalysts for Electrochemical Nitrogen Activation toward Sustainable Ammonia Synthesis
分子催化剂电化学活化氮气用于可持续合成氨 |
| 韩金秀, 薛皓, 付先彪 |
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Molecular Catalysts for Electrochemical Nitrogen Activation toward Sustainable Ammonia Synthesis |
| Jin-Xiu Han, Hao Xue, Xian-Biao Fu |
| Fig. 12. (a) Schematic of NH3 electrosynthesis from H2O and N2 using {SiFeIII3W9} with an alkali-metal cation. (b) Cyclic voltammograms of TBA{SiFe3W9} in the presence of ethanol under He and N2. (c) In situ UV-vis spectra of {SiFe3W9} under N2 with Li+ during electrolysis. Black: before electrolysis; red/blue/green/magenta: after 1/2/3/4 e− per TBA{SiFe3W9}. Reproduced with permission of Ref. [ |
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