分子催化剂电化学活化氮气用于可持续合成氨
Molecular Catalysts for Electrochemical Nitrogen Activation toward Sustainable Ammonia Synthesis
分子催化剂电化学活化氮气用于可持续合成氨 |
| 韩金秀, 薛皓, 付先彪 |
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Molecular Catalysts for Electrochemical Nitrogen Activation toward Sustainable Ammonia Synthesis |
| Jin-Xiu Han, Hao Xue, Xian-Biao Fu |
| Fig. 1. Physicochemical origins of N2 inertness and the orbital basis of transition-metal activation. (a) Representative molecular properties of N2, which highlight its strong N≡N bond, stable electronic structure, and high molecular symmetry. (b) Simplified molecular orbital diagram of N2. (c) Synergic σ-donation/π-back-donation for end-on M−N≡N binding. |
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