电催化乙二醇氧化制乙醇酸：机理与策略

张曼, 李雪, 彭馨玉, 王琳, 陈文文, 阳耀月

Electrocatalytic Oxidation of Ethylene Glycol to Glycolic Acid: From Mechanism and Catalyst Design to Emerging Neutral Electrolyte Systems

Man Zhang, Xue Li, Xin-Yu Peng, Lin Wang, Wen-Wen Chen, Yao-Yue Yang

Figure 6. (a) Effects of the doped Mn amount on TOF, particle size, and binding energy of Pt0[65]. Reproduced with permission from Ref. [65]. Copyright © 2021 Elsevier B.V. (b) Catalytic performance of EG oxidation on the PtMn/MCM-41 (In-70) catalyst. (c) Energy profiles and configuration diagrams of reactants (R), transition states (TS) and products (P) for the oxidation of EG to GA on the Pt (111) and Pt-Mn2O3 (111) models. (d) CVs of three catalysts in 1 mol·L-1 KOH + 1 mol·L-1 EG solution[41]. Reproduced with permission from Ref. [41]. Copyright © 2026 Elsevier B.V. (e) The schematic diagram of the surface-active sites poisoned by S2- for the two catalyst surfaces. (f) Electronic interaction of highly-dispersed Pd with defect-rich nickel disulfide nanoarrays for EG-to-GA[66]. Reproduced with permission from Ref. [66]. Copyright © 2026 Tsinghua University Press. In-situ Raman spectra of (g) Pd-Ni3-xCoxS2@NF and (h) Pd-Ni3S2@NF at various potentials in 1 mol·L-1 KOH with 0.5 mol·L-1 EG.