直接乙醇燃料电池阳极电催化剂的设计与优化：C-C键活化及C1途径选择性调控的研究进展与挑战

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秦愷池^a, 霍孟田^a, 梁宇^a, 朱思远^b, 邢子豪^a^,^*(

), 常进法^a^,^*(

)

Design and Optimization of Anode Catalysts for Direct Ethanol Fuel Cells: Advances and Challenges in C-C bond Activation and Selective Modulation of the C1 Pathway

Qin Kai-Chi^a, Huo Meng-Tian^a, Liang Yu^a, Zhu Si-Yuan^b, Xing Zi-Hao^a^,^*(

), Chang Jin-Fa^a^,^*(

)

Fig 8.. (A) Schematic representation of different crystalline phases of Pd₃Sn nanorod catalysts. (B) EOR free energy diagrams of Pd₃Sn nanorod catalysts with different crystalline phases. Reproduced with permission of Ref. [95]. Copyright 2021, Wiley-VCH. (C) HAADF-STEM and TEM image, and HAADF-STEM-EDS elemental mappings of PdAg catalyst. Reproduced with permission of Ref. [96]. Copyright 2024, Elsevier. (D) DFT calculations for a-PdCu and c-PdCu catalysts. Reproduced with permission of Ref. [97]. Copyright 2022, American Chemical Society.