直接乙醇燃料电池阳极电催化剂的设计与优化：C-C键活化及C1途径选择性调控的研究进展与挑战

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秦愷池^a, 霍孟田^a, 梁宇^a, 朱思远^b, 邢子豪^a^,^*(

), 常进法^a^,^*(

)

Design and Optimization of Anode Catalysts for Direct Ethanol Fuel Cells: Advances and Challenges in C-C bond Activation and Selective Modulation of the C1 Pathway

Qin Kai-Chi^a, Huo Meng-Tian^a, Liang Yu^a, Zhu Si-Yuan^b, Xing Zi-Hao^a^,^*(

), Chang Jin-Fa^a^,^*(

)

Fig 6.. (A) Reaction mechanism for the selective conversion of ethanol to acetic acid over Pd-Ni-P ternary nanocatalysts in alkaline media. Reproduced with permission of Ref. [84]. Copyright 2017, Springer Nature. (B) TEM characterization of P-PdMo bimetallene. Reproduced with permission of Ref. [86]. Copyright 2024, Elsevier. (C) The synthesis schematic of Pd/DB-Ti₃C₂. (D) The calculated EOR free‐energy profiles of two catalysts. Reproduced with permission of Ref. [87]. Copyright 2024, Wiley-VCH.