直接乙醇燃料电池阳极电催化剂的设计与优化：C-C键活化及C1途径选择性调控的研究进展与挑战

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秦愷池^a, 霍孟田^a, 梁宇^a, 朱思远^b, 邢子豪^a^,^*(

), 常进法^a^,^*(

)

Design and Optimization of Anode Catalysts for Direct Ethanol Fuel Cells: Advances and Challenges in C-C bond Activation and Selective Modulation of the C1 Pathway

Qin Kai-Chi^a, Huo Meng-Tian^a, Liang Yu^a, Zhu Si-Yuan^b, Xing Zi-Hao^a^,^*(

), Chang Jin-Fa^a^,^*(

)

Fig 5.. (A) EOR mechanism of different catalysts in an alkaline solution. Reproduced with permission of Ref. [71]. Copyright 2023, Springer Nature. (B) The potential energy profiles of CH₃CH₂OH_ad oxidation to CH₃CO_ad on the Pd(111), Pd₄/NbN(111) and Pd₄-SnO₂/NbN(111) surfaces. Reproduced with permission of Ref. [72]. Copyright 2023, Wiley-VCH. (C) Schematic route for the synthesis of 2D Pd-Au heterogeneous phase nanosheets. Reproduced with permission of Ref. [73]. Copyright 2021, Wiley-VCH. (D) TEM, magnified TEM, typical aberration-corrected HAADF-STEM and the corresponding elemental mapping images of PtCu-SnO₂. Reproduced with permission of Ref. [74]. Copyright 2024, Elsevier.