直接乙醇燃料电池阳极电催化剂的设计与优化：C-C键活化及C1途径选择性调控的研究进展与挑战

秦愷池, 霍孟田, 梁宇, 朱思远, 邢子豪, 常进法

Design and Optimization of Anode Catalysts for Direct Ethanol Fuel Cells: Advances and Challenges in C-C bond Activation and Selective Modulation of the C1 Pathway

Kai-Chi Qin, Meng-Tian Huo, Yu Liang, Si-Yuan Zhu, Zi-Hao Xing, Jin-Fa Chang

Fig 11. (A) Schematic diagram of the preparation process of PtBi@PtRh1 nanosheets. (B) Ethanol electrooxidation performance test of PtBi@PtRh1. (C) C-C bond breaking energy distribution of CH2CO intermediates on different Pt(110) surfaces. Reproduced with permission of Ref. [116]. Copyright 2021, Wiley-VCH. (D) FT-IR spectra of EOR on Rh7Pt1 PBML. (E) Free energy diagrams of EOR and ΔG from 2CO* to 2COOH* on Rh (111), Pt (111), RhPt (111) and RhPt (311) surfaces. Reproduced with permission of Ref. [117]. Copyright 2024, Royal Society of Chemistry.