直接乙醇燃料电池阳极电催化剂的设计与优化：C-C键活化及C1途径选择性调控的研究进展与挑战

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秦愷池^a, 霍孟田^a, 梁宇^a, 朱思远^b, 邢子豪^a^,^*(

), 常进法^a^,^*(

)

Design and Optimization of Anode Catalysts for Direct Ethanol Fuel Cells: Advances and Challenges in C-C bond Activation and Selective Modulation of the C1 Pathway

Qin Kai-Chi^a, Huo Meng-Tian^a, Liang Yu^a, Zhu Si-Yuan^b, Xing Zi-Hao^a^,^*(

), Chang Jin-Fa^a^,^*(

)

Fig 10.. (A) Schematic illustration of the fluorination-driven rearrangement of the LCE on Pd/N-C. (B) EOR mass activity comparison of different samples (left axis), retention of relative initial activity after 10,000 cycles (right axis). (C) CO₂ Faraday efficiency of different samples at different potentials. Reproduced with permission of Ref. [100]. Copyright 2021, Springer Nature. (D) C1-pathway of EOR on Pt/Al₂O₃@TiAl. (E) EOR path free energy diagrams on different models Reproduced with permission of Ref. [101]. Copyright 2023, Wiley-VCH.