金电极表面有序分子膜的电化学原位偏振调制红外反射光谱研究

苏章菲, 陈爱成, Jacek Lipkowski

PM IRRAS Studies of Organized Molecular Films at a Gold Electrode Surface

Zhang-Fei Su, Ai-Cheng Chen, Jacek Lipkowski

Figure 8. (A) Model of the DPhPC fBLM with embedded colicin E1. Reprinted with permission from Ref. [70]. Copyright 2019 American Chemical Society. (B) PM IRRAS spectrum of the DPhPC/colicin fBLM in the C=O stretching and amide I region and its deconvolution. Reprinted with permission from Ref. [70]. Copyright 2019 American Chemical Society. (C) Variation of the average tilt angle of α-helices in colicin (γcolicin) and the membrane resistance of the DPhPC/colicin fBLM (Rm) as a function of the electrode potential. Reprinted with permission from Ref. [70]. Copyright 2019 American Chemical Society. (D) Correlation between the changes of the tilt angle of α-helices on the electrode potential. Reprinted with permission from Ref. [70]. Copyright 2019 American Chemical Society.