电化学促进的镍催化的α-氰基乙酸酯的α-芳基化反应

李子萌, 李章健, 方萍, 梅天胜

Nickel-Catalyzed α-Arylation of α-Cyanoacetates Enabled by Electrochemistry

Zi-Meng Li, Zhang-Jian Li, Anat Milo, Ping Fang, Tian-Sheng Mei

Figure 10. Energy barriers of reductive eliminations from divalent Ni species (left) and trivalent Ni species (right) at PBE0-D3(BJ)/def2-TZVP-SMD(DMAc)//PBE0-D3(BJ)/def2-SVP-SMD(DMAc).