平衡、非平衡、交流状态下电化学双电层建模的初学者指南

张露露, 李琛坤, 黄俊

A Beginners’ Guide to Modelling of Electric Double Layer under Equilibrium, Nonequilibrium and AC Conditions

Lu-Lu Zhang, Chen-Kun Li, Jun Huang

Figure 7. Typical results of the BPB model with the asymmetric size effect, including the relationships between (A) the surface charge density and (B) the differential double-layer capacitance with the electrode potential. The results of the symmetric BPB model are shown in the blue circles, as γ+ = γ- = 1. The results at γ+ = 1 and γ- = 3 are shown in the red solid lines, while the results at γ+ =3 and γ- = 1 are shown in the yellow solid lines. The grey circles represent the results at γ+ = γ- = 3. The parameters for calculation are listed in Table 1. Matlab script of this model is provided in the supporting information. (color on line)