平衡、非平衡、交流状态下电化学双电层建模的初学者指南

张露露, 李琛坤, 黄俊

A Beginners’ Guide to Modelling of Electric Double Layer under Equilibrium, Nonequilibrium and AC Conditions

Lu-Lu Zhang, Chen-Kun Li, Jun Huang

Figure 12. Comparison between the AFT-calculated and the analytical impedance expressed in Eq. (127). Parameters used in calculation are as follows, c0 = 100 mol·m-3, k0 = 4.45× 10-5 mol·m-2·s-1, D = 3.2×10-11 m2·s-1, frequency range: 4.22×10-4 ~ 5×105 Hz, sampling frequency: 100*(excitation frequency), sampling duration: the reciprocal of sampling frequency. Matlab script of this model is provided in the supporting information.