宏观均相多孔电极电化学阻抗谱基础
李响1, 黄秋安1,2,*(
), 李伟恒2, 白玉轩1,2, 王佳1,2, 刘杨2, 赵玉峰2, 王娟1,*(), 张久俊2,*()
), 李伟恒2, 白玉轩1,2, 王佳1,2, 刘杨2, 赵玉峰2, 王娟1,*(), 张久俊2,*()
Fundamentals of Electrochemical Impedance Spectroscopy for Macrohomogeneous Porous Electrodes
Xiang Li1, Qiu-An Huang1,2,*(), Wei-Heng Li2, Yu-Xuan Bai1,2, Jia Wang1,2, Yang Liu2, Yu-Feng Zhao2, Juan Wang1,*(), Jiu-Jun Zhang2,*()
), Wei-Heng Li2, Yu-Xuan Bai1,2, Jia Wang1,2, Yang Liu2, Yu-Feng Zhao2, Juan Wang1,*(), Jiu-Jun Zhang2,*()
图13. σ1给定,多孔电极阻抗随Lp 的演变规律。σ1 = 1σ0时,(A) Z′-Z″图和(B) 局部放大图;σ1 = 10σ0时,(C) Z′-Z″图和(D)局部放大图;σ1 = 100σ0时,(E) Z′-Z″图和(F)局部放大图;σ1 = 1σ0,10σ0,100σ0时,(G) |Z|-f图和(H) θ-f图。（网络版彩图）
Figure 13. Under a given σ1, the evolution trend of the porous electrode impedance with respect to Lp. At σ1 = 1σ0, (A) Nyquist view and (B) Nyquist enlarged view; at σ1 = 10σ0, (C) Nyquist view and (D) Nyquist enlarged view; at σ1 = 100σ0, (E) Nyquist view and (F) Nyquist enlarged view, when σ1 = 1σ0,10σ0,100σ0, (G) |Z|-f diagrams and (H) θ-f diagrams. (color on line)
