惰性小分子电催化还原反应的电解液调控

李金翰, 程方益

Electrolyte Tailoring for Electrocatalytic Reduction of Stable Molecules

LI Jin-han, CHENG Fang-yi

图4 (A) 电解液对铜纳米立方体催化剂表面粗化的促进作用[58]. (B) 阴、阳离子共吸附对催化剂形貌及性能影响[26]. (C) 浓KOH电解液阳极电化学氧化制备Cu(OH)2纳米线[62]. (D), (E) 操作条件下铜纳米立方体催化剂的表面熟化机理[63].

Fig. 4 (A) Promoting effect of electrolyte on the roughening of the surface of Cu nanocube catalysts (Reprinted with permission from Ref.[58]. Copyright (2018) Wiley-VCH Verlag GmbH & Co. KGaA). (B) The effects of anion and cation co-adsorption on the morphology and performance of catalysts (Reprinted with permission from Ref.[26]. Copyright (2018) American Chemical Society). (C) Electrochemical oxidation to prepare Cu(OH)2 nanowires in concentrated KOH electrolyte (Reprinted with permission from Ref.[62]. Copyright (2018) American Chemical Society). (D), (E) Surface maturation mechanism of cubic Cu catalyst under operating conditions[63].