惰性小分子电催化还原反应的电解液调控

李金翰, 程方益

Electrolyte Tailoring for Electrocatalytic Reduction of Stable Molecules

LI Jin-han, CHENG Fang-yi

图2 (A) 碱金属离子调节表面pH及二氧化碳局部浓度[32]. (B) 碱金属离子诱导表面电场法向分布[34]. (C), (D) 碱金属离子对二氧化碳还原中间体吸附能的调节[26]. (E) 卤离子的特性吸附[36].

Fig. 2 (A) Alkali metal ions adjusting surface pH and local concentration of CO2 (Reprinted with permission from Ref.[32]. Copyright (2016) American Chemical Society). (B) Surface electric field induced by alkali metal ions in normal distribution (Reprinted with permission from Ref. [34]. Copyright (2017) American Chemical Society). (C), (D) Adsorption energy of CO2 reduction intermediates tailored by alkali metal ions (Reprinted with permission from Ref.[26]. Copyright (2018) American Chemical Society). (E) Specific adsorption of halides (Reprinted with permission from Ref.[36]. Copyright (2018) American Chemical Society).