Rutile TiO2  Nanosheet Arrays Planted on Magnetron Sputtered Ti Metal Layers for Efficient Perovskite Solar Cells

doi:10.13208/j.electrochem.161251

Abstract

Abstract:

In this work, vertical rutile titanium oxide (TiO₂) nanosheet arrays (NSAs) were firstly hydrothermally grown on the top of thin titanium (Ti) metal layers which were loaded on fluorine doped tin oxide (FTO) substrates by the DF magnetron sputtering deposition method. After an annealing post-treatment, the Ti metal layers were transformed into the compact TiO₂ layers with a strong connection between the rutile TiO₂ NSAs and the FTO substrates. For comparison, the rutile TiO₂ NSAs were similarly planted over two compact TiO₂ layers fabricated through atomic layer deposition (ALD) and spin coating (SC) methods, respectively. When served as the scaffold layers in perovskite solar cells (PSCs), the Ti-based TiO₂ NSAs showed the best cell performance due to the high quality of the TiO₂ NSA nanostructure and excellent interface contacts among the TiO₂ NSAs/TiO₂ compact layers/FTO substrate interface. Significantly, a highest cell efficiency of 11.82% was obtained after careful modification on the organization procedures for the PSC devices.

Key words: Ti metal layer, TiO_2 , nanosheet arrays, perovskite solar cells

CLC Number:

O646

Nang Zhang，Meidan Ye, Xiaoru Wen, Changjian Lin. Rutile TiO₂Nanosheet Arrays Planted on Magnetron Sputtered Ti Metal Layers for Efficient Perovskite Solar Cells[J]. Journal of Electrochemistry, 2017, 23(2): 226-237.

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Rutile TiO₂Nanosheet Arrays Planted on Magnetron Sputtered Ti Metal Layers for Efficient Perovskite Solar Cells

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