具有高效电化学储能的中空网状笼还原氧化石墨烯

doi:10.13208/j.electrochem.151245

电化学（中英文） ›› 2016, Vol. 22 ›› Issue (3): 278-287. doi: 10.13208/j.electrochem.151245

• 电化学获奖人优秀论文专辑 • 上一篇下一篇

具有高效电化学储能的中空网状笼还原氧化石墨烯

张翅，何序骏，李高仁*

中山大学化学与化学工程学院，广东广州 510275

收稿日期:2016-01-12 修回日期:2016-05-30 出版日期:2016-06-28 发布日期:2016-05-31
通讯作者: 李高仁 E-mail:ligaoren@mail.sysu.edu.cn
基金资助:
This work was supported by National Natural Science Foundation of China (No. 51173212), National Basic Research Program of China (No. 2015CB932304), Natural Science Foundation of Guangdong Province (Nos. S2013020012833 and 2016A010104004), and Fundamental Research Fund for the Central Universities (No. 16lgjc67).

Reduced Graphene Oxide (RGO) Hollow Network Cages for High-Performance Electrochemical Energy Storage

Chi Zhang, Xu-Jun He, Gao-Ren Li*

School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, China

Received:2016-01-12 Revised:2016-05-30 Published:2016-06-28 Online:2016-05-31
Contact: Gao-Ren Li E-mail:ligaoren@mail.sysu.edu.cn
Supported by:
This work was supported by National Natural Science Foundation of China (No. 51173212), National Basic Research Program of China (No. 2015CB932304), Natural Science Foundation of Guangdong Province (Nos. S2013020012833 and 2016A010104004), and Fundamental Research Fund for the Central Universities (No. 16lgjc67).

摘要/Abstract

摘要：

通过ZnO模板辅助电沉积法制备了中空网状笼还原氧化石墨烯，具有纳米管、多孔结构、网状结构和3D微米中空笼等多层次架构. 这样的结构能够同时促进电化学活性物种的传输，提高电极材料的利用率，以及提升超级电容器性能. 该类中空网状笼还原氧化石墨烯做超级充电器电极材料时表现出了优良的电化学性能，研究结果显示，在1.0 A•g^-1时比电容达到393 F•g^-1. 而且当电流密度从1.0 A•g^-1增加到20 A•g^-1，电容仅衰减了21.2%，10000周循环后比电容损失小于1%，表明具有优异的电容稳定性.

关键词: 还原氧化石墨烯, 多孔结构, 纳米片, 超级电容器

Abstract:

The reduced graphese oxide (RGO) hollow network cages were synthesized via zinc oxide (ZnO) template-assisted electrodeposition. The as-prepared RGO hollow network cages exhibited the multi-level architectures, from nano sheets, porous structures, networks, to 3D microscaled hollow cages, which can simultaneously optimize transport of electroactive species, utilization rate of electrode material, and super capacitive performance. Electrochemical measurements confirmed the superior performance of RGO hollow network cages for supercapacitors (SCs), such as high Csp (393 F•g^-1 at 1.0 A•g^-11), excellent rate capability (21.2% Csp loss from 1.0 to 20 A•g^-1), and superior cycling stability (< 1% Csp loss after 10000 cycles).

Key words: reduced graphene oxide, porous structure, nanotube, supercapacitor

中图分类号:

Q81
O646.54

Support info:

点击下载Supporting Information

张翅，何序骏，李高仁. 具有高效电化学储能的中空网状笼还原氧化石墨烯[J]. 电化学（中英文）, 2016, 22(3): 278-287.

Chi Zhang, Xu-Jun He, Gao-Ren Li. Reduced Graphene Oxide (RGO) Hollow Network Cages for High-Performance Electrochemical Energy Storage[J]. Journal of Electrochemistry, 2016, 22(3): 278-287.

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具有高效电化学储能的中空网状笼还原氧化石墨烯

Reduced Graphene Oxide (RGO) Hollow Network Cages for High-Performance Electrochemical Energy Storage

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