对磺酸基苯偶氮杯[4]芳烃电化学行为研究

doi:10.13208/j.electrochem.150604

电化学（中英文） ›› 2016, Vol. 22 ›› Issue (1): 37-42. doi: 10.13208/j.electrochem.150604

对磺酸基苯偶氮杯[4]芳烃电化学行为研究

杨星，陈平*

辽宁石油化工大学材料化学与材料科学学院，辽宁抚顺 113001

收稿日期:2015-06-04 修回日期:2015-10-14 出版日期:2016-02-29 发布日期:2015-10-19
通讯作者: 陈平 E-mail:chenping-fs@sohu.com
作者简介:陈平
基金资助:
教育部科学技术研究重点项目（No. 209031）资助

An Electrochemical Investigation of p-sulfophenylazo Calix[4]arene in a Buffer Solution

YANG Xing，CHEN Ping*

School of Chemistry and Materials Science, Liaoning Shihua University, Fushun 113001, Liaoning, China

Received:2015-06-04 Revised:2015-10-14 Published:2016-02-29 Online:2015-10-19
Contact: CHEN Ping E-mail:chenping-fs@sohu.com
About author:CHEN Ping

摘要/Abstract

摘要：

以杯[4]芳烃和对氨基苯磺酸为原料，经重氮化-偶联反应合成了对磺酸基苯偶氮杯[4]芳烃，并使用紫外吸收光谱、红外吸收光谱、核磁共振等技术对其进行表征分析. 首次以CH₃COOH-CH₃COONa为缓冲溶液，使用循环伏安法研究对磺酸基苯偶氮杯[4]芳烃的电化学行为. 结果表明，当扫描电位在-0.5 ~ 1 V时，有1对氧化还原峰，其中氧化峰电位为0.302 V，还原峰电位为-0.003 V，且峰电流与峰电位均与扫描速率呈线性关系，推测该峰的形成受扩散控制影响，反应为动力学准一级可逆反应. 进一步利用多种电化学手段研究该电极反应，并求得动力学参数，反应活化能为14.84 kJ•mol^-1.

关键词: 对磺酸基苯偶氮杯[4]芳烃, 循环伏安法, 玻碳电极, 电化学行为

Abstract:

The p-sulfophenylazo calix[4]arene was synthesized through the diazotization-coupling reaction between calix[4]arene and p-aminobenzene sulfonic acid. The UV-Vis spectroscopy, Infrared spectroscopy, and nuclear magnetic resonance (NMR) were used to characterize the as-prepared p-sulfophenylazo calix[4]arene. The electrochemical behaviors of p-sulfophenylazo calix[4]arene were investigated by cyclic voltammetry and chronoamperometry using CH₃COOH-CH₃COONa as a buffer solution. The result shows that the p-sulfophenylazo calix[4]arene exhibited a pair of redox peaks in a scan potential region of -0.5 ~ 1 V. The oxidation and reduction peak potentials were 0.302 V and -0.003 V, respectively, and changed with the scanning rates. In addition, the electrode reaction was studied by various electrochemical methods, and the kinetic parameters have also been obtained. The activation energy was found to be 14.84 kJ•mol^-1.

Key words: sulfophenylazo calix[4]arene, cyclic voltammetry, glassy carbon electrode, electrochemical behavior

中图分类号:

O646

杨星，陈平*. 对磺酸基苯偶氮杯[4]芳烃电化学行为研究[J]. 电化学（中英文）, 2016, 22(1): 37-42.

YANG Xing，CHEN Ping*. An Electrochemical Investigation of p-sulfophenylazo Calix[4]arene in a Buffer Solution[J]. Journal of Electrochemistry, 2016, 22(1): 37-42.

参考文献

[1] Yang C Y, Liu T T, Xu Y M, et al. Fluorescent ion optodes based on calixarene functionized boron dipyrromethene chromoionophore for simultaneous measurement of multi-electrolytes in biological samples[J]. Sensors and Actuactors B: Chemical, 2014, 192: 423-428.

[2] Akceylan E, Yilmaz M. Synthesis of calix[4]arene alkyl amine derivatives as new phase transfer catalysts for esterification reaction[J]. Tetrahedron, 2011, 67(34): 6240-6245.

[3] Lazzarotto M, Ferreira C I, Castellano E E, et al. Highly constrained guests in complexes of p-tert-butyl calix[6]arene dianion: Pentane-1,5-diammonium and choline[J]. Journal of Molecular Structure, 2014, 1067: 88-93.

[4] Ebdellia R, Dkhila S B, Azibc T, et al. Electrical, optical and morphological properties of a new chromogenic calix[4]arene derivative[J]. Synthetic Metals, 2014, 197: 112-118.

[5] Benounis M, Jaffrezic N, Mattelet C, et al. High sensitive surface plasmon resonance (SPR) sensor based on modified calix[4]arene self assembled monolayer for cadmium ions detection[J]. Materials Transactions, 2015, 56(4): 539-544.

[6] Liu Z C(刘智成), Wang H(王红), Yang R(杨睿), et al. Synthesis and application of phosphorous-containing calixarenes and their complexes[J]. Progress Chemistry(化学进展), 2011, 23(8): 1665-1682.

[7] Özk?nal? S. Spectroscopic and thermal properties of newly mixed azocalix[4]arene ester derivatives[J]. Dyes and Pigments, 2014, 107: 81-89.

[8] ?ener ?, ?ener N, Eri?kin S. Synthesis and absorption spectra of some novel hetaryl tetrakis azo calix[4]arene derivatives[J]. Dyes and Pigments, 2013, 96(1): 256-263.

[9] Fan P, Wan L, Shang Y, et al. Spectroscopic investigation of the interaction of water-soluble azo calix[4]arenes with bovine serum albumin[J]. Bioorganic Chemistry, 2015, 58: 88-95.

[10] Chawla H M, Gupta T. Novel bis-calix[4]arene based molecular probe for ferric iron through colorimetric, ratiometric, and fluorescence enhancement response[J]. Tetrahedron Letters, 2015, 56(6): 793-796.

[11] Liu L M(刘丽梅), Zhang D L(张岱良), Chen P(陈平). The study of electro chemical properties of sulfonic calix[4]arene[J]. Journal of Liaoning Shihua University(辽宁石油化工大学学报), 2014, 34(3): 1-4.

[12] Pailleret A, Herzog G, Arrigan D W M. Electrochemical activity of phenolic calixarenes[J]. Electrochemistry communications, 2003, 5(1): 68-72.

[13] Jing A H(景爱华), Zhang S S(张书胜), Ye B X(冶保献). Study on the electrochemistry of sulfonatocalyx[6]arene at glassy carbon electrode[J]. Journal of Tianing Normal University(Natural Science Edition)(天津师范大学学报: 自然科学版), 2003, 23(3): 12-15.

[14] Zhang Y Z(张亚洲), Liu L M(刘丽梅), Chen P(陈平). Synthesis of water-soluble nitrogen containing calixarene[J]. Journal of Petrochemical Universities(石油化工高等学校学报), 2013, 26(3): 13-17.

[15] Qiao Q D(乔庆东), Li Q(李琪). Electrochemical behaviors of ferrocene using cyclic voltammetry[J]. Journal of Liaoning Shihua University(辽宁石油化工大学学报), 2014, 34(3): 5-7.

[16] Li L M(李丽敏), Sun T L(孙天麟), Gao H X(高洪霞). Research on electric chemical property of 4-(2-thiazole)-metaphenylene diahydroxybenzene[J]. Journal of Liaocheng Teachers College(Natural Science Edition)(聊城师院学报:自然科学版),1997, 10(1): 65-70.

[17] Li Y H(李玉红), Liu H X(刘焕新), Xu B(许兵). The culture of tobacco suspension cells and the isolation of organelles[J]. Journal of Capital Normal University(Natural Science Edition)(首都师范大学学报: 自然科学版), 2007, 28(2): 54-57.

对磺酸基苯偶氮杯[4]芳烃电化学行为研究

An Electrochemical Investigation of p-sulfophenylazo Calix[4]arene in a Buffer Solution

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

[1]	戴昭霞, 郑大江, 宋光铃, 冯丹青, 苏培. 不同电位下极化后的纯钛表面生物污损行为[J]. 电化学（中英文）, 2022, 28(5): 2109061-.
[2]	杨育霖, 孙杰, 周添, 李吉刚, 卫寿平. 铂片电极表面芥子气伏安行为研究[J]. 电化学（中英文）, 2022, 28(5): 2105071-.
[3]	战充波, 张润佳, 付旭, 孙海静, 周欣, 王保杰, 孙杰. 氯离子对ChCl-Urea低共熔溶剂中银电沉积的电化学行为影响[J]. 电化学（中英文）, 2022, 28(5): 2111151-.
[4]	蔡雪凡, 孙升. 多孔电极电池的循环伏安法模拟[J]. 电化学（中英文）, 2021, 27(6): 646-657.
[5]	程蕾, 闫普选, 樊友军, 邹华红, 梁宏. 玻碳电极界面的阻抗谱数学表达及定量分析[J]. 电化学（中英文）, 2021, 27(5): 518-528.
[6]	邢逸飞, 李娜, 温晓芳, 韩宏彦, 崔敏, 张聪, 任聚杰, 籍雪平. 基于取代型多酸复合材料的多巴胺电化学检测[J]. 电化学（中英文）, 2020, 26(6): 890-899.
[7]	凌云, 汤儆, 刘国坤, 宗铖. 暂态电化学表面增强拉曼光谱研究对硝基苯硫酚分子的电化学还原过程[J]. 电化学（中英文）, 2019, 25(6): 731-739.
[8]	李明雪, 史杭, 刘佳, 张檬, 周剑章, 吴德印, 田中群. 金电极上偶氮腺嘌呤的电化学行为研究[J]. 电化学（中英文）, 2019, 25(6): 651-659.
[9]	董鹏飞，李娜，赵海燕，崔敏，张聪，任聚杰，藉雪平. Keggin 型磷钨酸盐修饰碳糊电极传感多巴胺的研究[J]. 电化学（中英文）, 2018, 24(5): 555-562.
[10]	Hisham Hamzah,Guy Denuault,Philip Bartlett,Aleksandra Pinczewska,Jeremy Kilburn. 乙腈/碳酸氢钠溶液混合物电嫁接叔丁氧羟基-乙二胺[J]. 电化学（中英文）, 2017, 23(2): 130-140.
[11]	郑艳洁，姚宏，翁少煌，彭花萍，龚仕文，黄莉，戴强，林新华. 硫酸特布他林在聚铬黑T修饰电极上的电化学行为及其测定[J]. 电化学（中英文）, 2016, 22(6): 617-623.
[12]	宋秀丽, 贾瑞龙, 董文燕, 梁镇海. 乙炔电催化氧化制备草酸的机理研究[J]. 电化学（中英文）, 2015, 21(4): 353-361.
[13]	李作鹏，温雅琼，武美霞，郭永*. 离子液体限域于硅胶纳米孔道中的电化学行为研究(英文)[J]. 电化学（中英文）, 2014, 20(2): 121-127.
[14]	M. Rostom Ali*, Md. Ziaur Rahman, S. SankarSaha. 基于氯化胆碱离子液体的铜电沉积研究（英文）[J]. 电化学（中英文）, 2014, 20(2): 139-145.
[15]	郑艳洁，刘爱林，雷云，林新华*. 丹皮酚在聚苏丹红Ⅲ/GC电极上的电化学行为及测定[J]. 电化学（中英文）, 2013, 19(4): 383-387.